1,1'-Diadamantyl ketone

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-367.8 ± 5.2kJ/molCcbAbboud, Jimenez, et al., 1992 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-476.8 ± 4.9kJ/molCcbAbboud, Jimenez, et al., 1992ALS
Quantity Value Units Method Reference Comment
Δcsolid-12074.4 ± 4.0kJ/molCcbAbboud, Jimenez, et al., 1992Corresponding Δfsolid = -476.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
355.2298.15Abboud, Jimenez, et al., 1992DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub109.0 ± 1.8kJ/molVAbboud, Jimenez, et al., 1992ALS
Δsub109.0 ± 1.8kJ/molMEAbboud, Jimenez, et al., 1992Based on data from 362. - 378.8 K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
15.7470.Victoria García, Isabel Redondo, et al., 1997AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

Quantity Value Units Method Reference Comment
Proton affinity (review)894.3kJ/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity862.4kJ/molN/AHunter and Lias, 1998 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Abboud, Jimenez, et al., 1992
Abboud, J.-L.; Jimenez, P.; Roux, M.V.; Turrion, C.; Lopez-Mardingo, C.; Sanz, G., Structural effects on the thermochemical properties of carbonyl compounds. II. Enthalpies of combustion, vapour pressures and enthalpies of sublimation, and standard enthalpies of formation in the gaseous phase, of 1-adamantyl methyl ketone and of 1,1'-diadamantyl ketone, J. Chem. Thermodyn., 1992, 24, 217-223. [all data]

Victoria García, Isabel Redondo, et al., 1997
Victoria García, M.; Isabel Redondo, M.; Victoria Roux, M., Vibrational spectra and phase transitions in 1,1´-diadamantyl ketone, Faraday Trans., 1997, 93, 15, 2509-2513, https://doi.org/10.1039/a701658a . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]


Notes

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