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CF3S


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

26393.16 ± 0.02 gas A-X 339 380 Powers, Pushkarsky, et al., 1995
Powers, Pushkarsky, et al., 1997
Yang, Williamson, et al., 1997


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CF stretch 990.5 gas LF FD Powers, Pushkarsky, et al., 1997
Yang, Williamson, et al., 1997
2 CF3 umbrella 737.7 gas LF FD Powers, Pushkarsky, et al., 1997
Yang, Williamson, et al., 1997
3 CS stretch 310.2 gas LF FD Powers, Pushkarsky, et al., 1995
Powers, Pushkarsky, et al., 1997
Yang, Williamson, et al., 1997
e 5 CF3 deformation 548 gas LF FD Powers, Pushkarsky, et al., 1997
Yang, Williamson, et al., 1997
6 CF3 rock 281.4 gas LF FD Powers, Pushkarsky, et al., 1997
Yang, Williamson, et al., 1997

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CF3 s-stretch 1142 w gas LF Backholtz, Yang, et al., 1999
2 CS stretch 765 w gas LF Backholtz, Yang, et al., 1999
3 CF3 umbrella 449 w gas LF Backholtz, Yang, et al., 1999
e 5 CF3 deform. 536 w gas LF Backholtz, Yang, et al., 1999
6 FCS deform. 320 w gas LF Backholtz, Yang, et al., 1999

Additional references: Jacox, 1998, page 303; Jacox, 2003, page 302

Notes

wWeak

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Powers, Pushkarsky, et al., 1995
Powers, D.E.; Pushkarsky, M.; Miller, T.A., Laser-induced fluorescence and fluorescence depletion spectroscopy of the jet-cooled CF3S radical, Chem. Phys. Lett., 1995, 247, 4-6, 548, https://doi.org/10.1016/S0009-2614(95)01252-4 . [all data]

Powers, Pushkarsky, et al., 1997
Powers, D.E.; Pushkarsky, M.B.; Yang, M.-C.; Miller, T.A., Spectroscopy and Photochemical Dynamics of the CF, J. Phys. Chem. A, 1997, 101, 51, 9846, https://doi.org/10.1021/jp972202w . [all data]

Yang, Williamson, et al., 1997
Yang, M.-C.; Williamson, J.M.; Miller, T.A., Rotational Analyses of the Laser Induced Fluorescence Excitation Spectra of Jet-Cooled CF3O and CF3S, J. Mol. Spectrosc., 1997, 186, 1, 1, https://doi.org/10.1006/jmsp.1997.7429 . [all data]

Backholtz, Yang, et al., 1999
Backholtz, T.A.; Yang, M.-C.; Miller, T.A., Jahn---Teller coupling in the [Xtilde], Mol. Phys., 1999, 97, 1-2, 239, https://doi.org/10.1080/00268979909482826 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References