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Diindium monoxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.4 ± 0.2EIGomez, Chatillon, et al., 1982LBLHLM
8.3 ± 0.3EIMakowiecki, Lynch, et al., 1971LLK
9. ± 0.5EIShchukarev, Semenov, et al., 1969RDSH
8.0 ± 0.5EIBurns, 1966RDSH
7.8 ± 0.5EIBurns, DeMaria, et al., 1963RDSH
10.3 ± 0.5EIShchukarev, Semenov, et al., 1962RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
In+9.5 ± 0.5?EIGomez, Chatillon, et al., 1982LBLHLM
In2+15. ± 0.5OEIShchukarev, Semenov, et al., 1969RDSH

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 32699 ± 15 Ar C-X 300 306 Douglas, Hauge, et al., 1983
To = 31854 ± 15 Kr C-X 306 314 Douglas, Hauge, et al., 1983


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

1 Sym. stretch 576 Ar AB Douglas, Hauge, et al., 1983
2 Bend 139 Kr AB Douglas, Hauge, et al., 1983

State:   B2


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 26524.53 gas B2-X 373 377 Lakin, van den Hoek, et al., 1997

State:   B1


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 25815 gas B1-X 380 388 Lakin, van den Hoek, et al., 1997
To = 25644 ± 15 Kr Douglas, Hauge, et al., 1983
To = 25535 ± 15 Kr Douglas, Hauge, et al., 1983


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 InO s-stretch 219.2 gas AB Lakin, van den Hoek, et al., 1997
2 Bend 94 T gas AB Lakin, van den Hoek, et al., 1997

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 19260 ± 15 Kr Douglas, Hauge, et al., 1983

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 InO s-stretch 222 gas LF Lakin, van den Hoek, et al., 1997
Piu 2 Bend 52 H gas LF Lakin, van den Hoek, et al., 1997
Sigmau+ 3 InO a-stretch 745.4 Ne IR Makowiecki, Lynch, et al., 1971
3 InO a-stretch 735.2 Ar IR Makowiecki, Lynch, et al., 1971
Hinchcliffe and Ogden, 1973
Zehe, Lynch, et al., 1979
Burkholder, Yustein, et al., 1992
3 InO a-stretch 728.2 Kr IR Makowiecki, Lynch, et al., 1971
3 InO a-stretch 722.4 N2 IR Hinchcliffe and Ogden, 1969
Makowiecki, Lynch, et al., 1971
Hinchcliffe and Ogden, 1971
Hinchcliffe and Ogden, 1973
Zehe, Lynch, et al., 1979

Additional references: Jacox, 1994, page 64; Jacox, 2003, page 81

Notes

H(1/2)(2nu)
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gomez, Chatillon, et al., 1982
Gomez, M.; Chatillon, C.; Allibert, M., Thermodynamics of gaseous and condensed indium oxides by mass spectrometry with controlled oxygen oressure, J. Chem. Thermodyn., 1982, 14, 447. [all data]

Makowiecki, Lynch, et al., 1971
Makowiecki, D.M.; Lynch, D.A.; Carlson, K.D., Infrared spectra of the aluminum family suboxides, J. Phys. Chem., 1971, 75, 1963. [all data]

Shchukarev, Semenov, et al., 1969
Shchukarev, S.A.; Semenov, G.A.; Rat'kovskii, I.A., A thermal investigation of the evaporation of gallium and indium oxides, Zh. Neorgan. Khim. 14,, 1969, 1. [all data]

Burns, 1966
Burns, R.P., Systematics of the evaporation coefficient Al2O3, Ga2O3, In2O3, J. Chem. Phys., 1966, 44, 3307. [all data]

Burns, DeMaria, et al., 1963
Burns, R.P.; DeMaria, G.; Drowart, J.; Inghram, M.G., Mass spectrometric investigation of the vaporization of In2O3, J. Chem. Phys., 1963, 38, 1035. [all data]

Shchukarev, Semenov, et al., 1962
Shchukarev, S.A.; Semenov, G.A.; Rat'kovskii, I.A., Study of the evaporation of gallium, indium, and thallium with the aid of the mass spectrometer, Zh. Prikl. Khim., 1962, 35, 1454, In original 1401. [all data]

Douglas, Hauge, et al., 1983
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., High Temp. Sci., 1983, 16, 35. [all data]

Lakin, van den Hoek, et al., 1997
Lakin, N.M.; van den Hoek, G.; Beattie, I.R.; Brown, J.M., The identification of In[sub 2]O in the gas phase by high resolution electronic spectroscopy, J. Chem. Phys., 1997, 107, 11, 4439, https://doi.org/10.1063/1.474786 . [all data]

Hinchcliffe and Ogden, 1973
Hinchcliffe, A.J.; Ogden, J.S., Matrix isolation studies on the gallium-indium-oxygen system. Infrared spectra and structures of molecular gallium(I) oxide, indium(I) oxide and indium gallium suboxide (InOGa), J. Phys. Chem., 1973, 77, 21, 2537, https://doi.org/10.1021/j100907a010 . [all data]

Zehe, Lynch, et al., 1979
Zehe, M.J.; Lynch, D.A., Jr.; Kelsall, B.J.; Carlson, K.D., Matrix reactions of molecular oxygen with indium and gallium atoms, J. Phys. Chem., 1979, 83, 6, 656, https://doi.org/10.1021/j100469a004 . [all data]

Burkholder, Yustein, et al., 1992
Burkholder, T.R.; Yustein, J.T.; Andrews, L., Reactions of pulsed laser evaporated gallium and indium atoms with molecular oxygen: matrix infrared spectra of new gallium dioxide and indium dioxide species, J. Phys. Chem., 1992, 96, 25, 10189, https://doi.org/10.1021/j100204a019 . [all data]

Hinchcliffe and Ogden, 1969
Hinchcliffe, A.J.; Ogden, J.S., Chem. Commun., 1969, 1053. [all data]

Hinchcliffe and Ogden, 1971
Hinchcliffe, A.J.; Ogden, J.S., Vibrational analysis for the molecules gallium oxide, indium oxide, and thallium oxide. Comment, J. Phys. Chem., 1971, 75, 25, 3908, https://doi.org/10.1021/j100694a030 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References