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PO2 anion


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 27600 ± 80 gas Xu, de Beer, et al., 1996

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 Bend 520 T gas PE Xu, de Beer, et al., 1996
b2 3 PO a-stretch 1198.6 Ar IR Mielke, McCluskey, et al., 1990
Bauschlicher, Zhou, et al., 2000

Additional references: Jacox, 1994, page 103; Jacox, 1998, page 199; Jacox, 2003, page 141

Notes

TTentative assignment or approximate value
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Xu, de Beer, et al., 1996
Xu, C.; de Beer, E.; Neumark, D.M., Photoelectron spectroscopy of PO-2, J. Chem. Phys., 1996, 104, 7, 2749, https://doi.org/10.1063/1.470983 . [all data]

Mielke, McCluskey, et al., 1990
Mielke, Z.; McCluskey, M.; Andrews, L., Matrix reactions of P2 and O3 molecules, Chem. Phys. Lett., 1990, 165, 2-3, 146, https://doi.org/10.1016/0009-2614(90)85420-H . [all data]

Bauschlicher, Zhou, et al., 2000
Bauschlicher, C.W., Jr.; Zhou, M.; Andrews, L., A Study of the Products of the Reaction of Phosphorus and Dioxygen, J. Phys. Chem. A, 2000, 104, 16, 3566, https://doi.org/10.1021/jp993623b . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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