CH3SiH=CH2

• Formula: C₂H₆Si
• Molecular weight: 58.1545
• CAS Registry Number: 38063-40-0
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 + C₂H₆Si = ( • C₂H₆Si)

By formula: Fe⁺ + C₂H₆Si = (Fe⁺ • C₂H₆Si)

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 + C₂H₆Si = ( • C₂H₆Si)

By formula: Fe⁺ + C₂H₆Si = (Fe⁺ • C₂H₆Si)

Vibrational and/or electronic energy levels

Go To: Top, Reaction thermochemistry data, Ion clustering data, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?

State:   ?

State:   X

Additional references: Jacox, 1994, page 399; Jacox, 2003, page 385; Khabashesku, Kudin, et al., 1998

Notes

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R., Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046 . [all data]

Vatsa, Kumar, et al., 1996
Vatsa, R.K.; Kumar, A.; Naik, P.D.; Upadhyaya, H.P., et al., UV spectrum and decay kinetics of transient methylsilene produced in the 193 nm photolysis of gaseous 1-methyl-1-silacyclobutane, Chem. Phys. Lett., 1996, 255, 1-3, 129, https://doi.org/10.1016/0009-2614(96)00342-9 . [all data]

Drahnak, Michl, et al., 1981
Drahnak, T.J.; Michl, J.; West, R., Photoisomerization of dimethylsilylene to 2-silapropene and thermal reversion to dimethylsilylene, J. Am. Chem. Soc., 1981, 103, 7, 1845, https://doi.org/10.1021/ja00397a047 . [all data]

Arrington, Klingensmith, et al., 1984
Arrington, C.A.; Klingensmith, K.A.; West, R.; Michl, J., Polarized infrared spectroscopy of matrix-isolated dimethylsilylene and 1-methylsilene, J. Am. Chem. Soc., 1984, 106, 3, 525, https://doi.org/10.1021/ja00315a010 . [all data]

Maier, Mihm, et al., 1984
Maier, G.; Mihm, G.; Reisenauer, H.P.; Littmann, D., Hetero-π-Systeme, 9. Über die Beziehungen zwischen Silaethenen und Methylsilylenen, Chem. Ber., 1984, 117, 7, 2369, https://doi.org/10.1002/cber.19841170709 . [all data]

Raabe, Vancik, et al., 1986
Raabe, G.; Vancik, H.; West, R.; Michl, J., IR transition moment directions in matrix-isolated dimethylsilylene and 1-methylsilene, J. Am. Chem. Soc., 1986, 108, 4, 671, https://doi.org/10.1021/ja00264a017 . [all data]

Reisenauer, Mihm, et al., 1982
Reisenauer, H.P.; Mihm, G.; Maier, G., Reversible Photoisomerisierung zwischen Silaethenen und Methylsilylenen (Methylsilandiylen), Angew. Chem., 1982, 94, 11, 864, https://doi.org/10.1002/ange.19820941110 . [all data]

Trommer, Sander, et al., 1993
Trommer, M.; Sander, W.; Patyk, A., Oxidation of methylsilenes with molecular oxygen. A matrix isolation study, J. Am. Chem. Soc., 1993, 115, 25, 11775, https://doi.org/10.1021/ja00078a016 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Khabashesku, Kudin, et al., 1998
Khabashesku, V.N.; Kudin, K.N.; Margrave, J.L., Vibrational analysis of infrared spectra of matrix-isolated transient silenes on basis of density functional theory calculations, J. Mol. Struct., 1998, 443, 1-3, 175, https://doi.org/10.1016/S0022-2860(97)00398-0 . [all data]

Notes

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• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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