Ozone anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-14.610 ± 0.060kcal/molR-EANovich, Engelking, et al., 1979 

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
Δr2.70 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.4cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.80 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

O3- + Oxygen = (O3- • Oxygen)

By formula: O3- + O2 = (O3- • O2)

Quantity Value Units Method Reference Comment
Δr2.10 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-3.60 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

(O3- • 4Oxygen) + Oxygen = (O3- • 5Oxygen)

By formula: (O3- • 4O2) + O2 = (O3- • 5O2)

Quantity Value Units Method Reference Comment
Δr1.54kcal/molPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr16.4cal/mol*KPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M

(O3- • 2Nitrogen) + Nitrogen = (O3- • 3Nitrogen)

By formula: (O3- • 2N2) + N2 = (O3- • 3N2)

Quantity Value Units Method Reference Comment
Δr2.5 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Oxygen) + Oxygen = (O3- • 3Oxygen)

By formula: (O3- • 2O2) + O2 = (O3- • 3O2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr20.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Nitrogen) + Nitrogen = (O3- • 4Nitrogen)

By formula: (O3- • 3N2) + N2 = (O3- • 4N2)

Quantity Value Units Method Reference Comment
Δr2.3 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Oxygen) + Oxygen = (O3- • 4Oxygen)

By formula: (O3- • 3O2) + O2 = (O3- • 4O2)

Quantity Value Units Method Reference Comment
Δr1.6 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr15.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Nitrogen) + Nitrogen = (O3- • 5Nitrogen)

By formula: (O3- • 4N2) + N2 = (O3- • 5N2)

Quantity Value Units Method Reference Comment
Δr2.1 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr18.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 5Nitrogen) + Nitrogen = (O3- • 6Nitrogen)

By formula: (O3- • 5N2) + N2 = (O3- • 6N2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 6Nitrogen) + Nitrogen = (O3- • 7Nitrogen)

By formula: (O3- • 6N2) + N2 = (O3- • 7N2)

Quantity Value Units Method Reference Comment
Δr1.8 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr18.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 7Nitrogen) + Nitrogen = (O3- • 8Nitrogen)

By formula: (O3- • 7N2) + N2 = (O3- • 8N2)

Quantity Value Units Method Reference Comment
Δr1.7 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr17.5cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 8Nitrogen) + Nitrogen = (O3- • 9Nitrogen)

By formula: (O3- • 8N2) + N2 = (O3- • 9N2)

Quantity Value Units Method Reference Comment
Δr1.5 ± 0.4kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr16.9cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • Nitrogen) + Nitrogen = (O3- • 2Nitrogen)

By formula: (O3- • N2) + N2 = (O3- • 2N2)

Quantity Value Units Method Reference Comment
Δr2.6 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.6cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • Oxygen) + Oxygen = (O3- • 2Oxygen)

By formula: (O3- • O2) + O2 = (O3- • 2O2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Water) + Water = (O3- • 3Water)

By formula: (O3- • 2H2O) + H2O = (O3- • 3H2O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O3- • Water) + Water = (O3- • 2Water)

By formula: (O3- • H2O) + H2O = (O3- • 2H2O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2296.FAFehsenfeld and Ferguson, 1974gas phase; M

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(O3- • Water) + Water = (O3- • 2Water)

By formula: (O3- • H2O) + H2O = (O3- • 2H2O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O3- • 2Water) + Water = (O3- • 3Water)

By formula: (O3- • 2H2O) + H2O = (O3- • 3H2O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5296.FAFehsenfeld and Ferguson, 1974gas phase; M

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
Δr2.70 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.4cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.80 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

(O3- • Nitrogen) + Nitrogen = (O3- • 2Nitrogen)

By formula: (O3- • N2) + N2 = (O3- • 2N2)

Quantity Value Units Method Reference Comment
Δr2.6 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.6cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Nitrogen) + Nitrogen = (O3- • 3Nitrogen)

By formula: (O3- • 2N2) + N2 = (O3- • 3N2)

Quantity Value Units Method Reference Comment
Δr2.5 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Nitrogen) + Nitrogen = (O3- • 4Nitrogen)

By formula: (O3- • 3N2) + N2 = (O3- • 4N2)

Quantity Value Units Method Reference Comment
Δr2.3 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Nitrogen) + Nitrogen = (O3- • 5Nitrogen)

By formula: (O3- • 4N2) + N2 = (O3- • 5N2)

Quantity Value Units Method Reference Comment
Δr2.1 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr18.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 5Nitrogen) + Nitrogen = (O3- • 6Nitrogen)

By formula: (O3- • 5N2) + N2 = (O3- • 6N2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 6Nitrogen) + Nitrogen = (O3- • 7Nitrogen)

By formula: (O3- • 6N2) + N2 = (O3- • 7N2)

Quantity Value Units Method Reference Comment
Δr1.8 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr18.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 7Nitrogen) + Nitrogen = (O3- • 8Nitrogen)

By formula: (O3- • 7N2) + N2 = (O3- • 8N2)

Quantity Value Units Method Reference Comment
Δr1.7 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr17.5cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 8Nitrogen) + Nitrogen = (O3- • 9Nitrogen)

By formula: (O3- • 8N2) + N2 = (O3- • 9N2)

Quantity Value Units Method Reference Comment
Δr1.5 ± 0.4kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr16.9cal/mol*KPHPMSHiraoka, 1988gas phase; M

O3- + Oxygen = (O3- • Oxygen)

By formula: O3- + O2 = (O3- • O2)

Quantity Value Units Method Reference Comment
Δr2.10 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-3.60 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

(O3- • Oxygen) + Oxygen = (O3- • 2Oxygen)

By formula: (O3- • O2) + O2 = (O3- • 2O2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Oxygen) + Oxygen = (O3- • 3Oxygen)

By formula: (O3- • 2O2) + O2 = (O3- • 3O2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr20.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Oxygen) + Oxygen = (O3- • 4Oxygen)

By formula: (O3- • 3O2) + O2 = (O3- • 4O2)

Quantity Value Units Method Reference Comment
Δr1.6 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr15.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Oxygen) + Oxygen = (O3- • 5Oxygen)

By formula: (O3- • 4O2) + O2 = (O3- • 5O2)

Quantity Value Units Method Reference Comment
Δr1.54kcal/molPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr16.4cal/mol*KPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M

Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 21420 ± 40 gas Hiller and Vestal, 1981


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 760 ± 20 gas PF Hiller and Vestal, 1981
2 Bend 190 ± 20 gas PF Hiller and Vestal, 1981

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Td = 16970 ± 20 gas Novich, Engelking, et al., 1979
Wang, Woo, et al., 1987

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 16508 ± 16 gas Cosby, Moseley, et al., 1978
Hiller and Vestal, 1981


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 815 ± 10 gas PF Cosby, Moseley, et al., 1978
Hiller and Vestal, 1981
2 Bend 275 ± 10 gas PF Cosby, Moseley, et al., 1978
Hiller and Vestal, 1981

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 975 ± 50 gas PD PF Cosby, Moseley, et al., 1978
Novich, Engelking, et al., 1979
Hiller and Vestal, 1981
1 Sym. stretch 975 ± 50 gas PE Arnold, Xu, et al., 1994
1 Sym. stretch 1016 Cs Ar Ra Andrews, 1973
Andrews and Spiker, 1973
1 Sym. stretch 1011 Na Ar Ra Andrews, 1973
Andrews and Spiker, 1973
2 Bend 550 ± 50 gas PD PF Novich, Engelking, et al., 1979
Hiller and Vestal, 1981
2 Bend 550 ± 50 gas PE Arnold, Xu, et al., 1994
2 Bend 600 w Cs Ar IR Spiker and Andrews, 1973
b2 3 Asym. stretch 880 ± 50 gas PE Arnold, Xu, et al., 1994
3 Asym. stretch 797 ± 5 A gas PF Bopp, Alexandrova, et al., 2009
3 Asym. stretch 796.3 Ne IR Thompson and Jacox, 1989
Lugez, Thompson, et al., 1996
3 Asym. stretch 804.3 Ar IR Andrews, Ault, et al., 1975
Wight, Ault, et al., 1976
3 Asym. stretch 789 s Cs Ar IR Jacox and Milligan, 1972
Spiker and Andrews, 1973
3 Asym. stretch 802 s Cs Ar IR Jacox and Milligan, 1972
Spiker and Andrews, 1973
3 Asym. stretch 802 s Na Ar IR Jacox and Milligan, 1972, 2
Jacox and Milligan, 1972
Spiker and Andrews, 1973

Additional references: Jacox, 1994, page 109; Jacox, 1998, page 203

Notes

wWeak
sStrong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
dPhotodissociation threshold
NaInteraction with sodium.
CsInteraction with cesium
A0~1 cm-1 uncertainty

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O3-, J. Chem. Phys., 1979, 70, 2652. [all data]

Hiraoka, 1988
Hiraoka, K., Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Hiller and Vestal, 1981
Hiller, J.F.; Vestal, M.L., Laser Photodissociation of O3- by Triple Quadrupole Mass Spectrometry, J. Chem. Phys., 1981, 74, 11, 6096, https://doi.org/10.1063/1.441053 . [all data]

Wang, Woo, et al., 1987
Wang, L.J.; Woo, S.B.; Helmy, E.M., Laser photodetachment of O_{3} ^{-}, Phys. Rev. A, 1987, 35, 2, 759, https://doi.org/10.1103/PhysRevA.35.759 . [all data]

Cosby, Moseley, et al., 1978
Cosby, P.C.; Moseley, J.T.; Peterson, J.R.; Ling, J.H., Photodissociation spectroscopy of O3, J. Chem. Phys., 1978, 69, 2771. [all data]

Arnold, Xu, et al., 1994
Arnold, D.W.; Xu, C.S.; Kim, E.H.; Neumark, D.M., Study of low-lying electronic states of ozone by anion photoelectron spectroscopy of O-3(-), J. Chem. Phys., 1994, 101, 2, 912, https://doi.org/10.1063/1.467745 . [all data]

Andrews, 1973
Andrews, L., Resonance Raman spectrum of the matrix isolated ozonide ion in the species metal(+) ozonide(-), J. Am. Chem. Soc., 1973, 95, 14, 4487, https://doi.org/10.1021/ja00795a003 . [all data]

Andrews and Spiker, 1973
Andrews, L.; Spiker, R.C., Jr., Resonance Raman spectrum and vibrational analysis of the ozonide ion in the argon matrix-isolated M[sup +]O[sub 3][sup -] species, J. Chem. Phys., 1973, 59, 4, 1863, https://doi.org/10.1063/1.1680271 . [all data]

Spiker and Andrews, 1973
Spiker, R.C., Jr.; Andrews, L., Matrix reactions of alkali metal atoms with ozone: Infrared spectra of the alkali metal ozonide molecules, J. Chem. Phys., 1973, 59, 4, 1851, https://doi.org/10.1063/1.1680270 . [all data]

Bopp, Alexandrova, et al., 2009
Bopp, J.C.; Alexandrova, A.N.; Elliott, B.M.; Herden, T.; Johnson, M.A., Vibrational predissociation spectra of the , n=3--10, 12 clusters: Even--odd alternation in the core ion, Int. J. Mass Spectrom., 2009, 283, 1-3, 94, https://doi.org/10.1016/j.ijms.2009.02.003 . [all data]

Thompson and Jacox, 1989
Thompson, W.E.; Jacox, M.E., The vibrational spectra of molecular ions isolated in solid neon. II. O+4 and O-4, J. Chem. Phys., 1989, 91, 7, 3826, https://doi.org/10.1063/1.456868 . [all data]

Lugez, Thompson, et al., 1996
Lugez, C.L.; Thompson, W.E.; Jacox, M.E., Matrix isolation study of the interaction of excited neon atoms with O3: Infrared spectrum of O-3 and evidence for the stabilization of O2•••O+4, J. Chem. Phys., 1996, 105, 6, 2153, https://doi.org/10.1063/1.472533 . [all data]

Andrews, Ault, et al., 1975
Andrews, L.; Ault, B.S.; Grzybowski, J.M.; Allen, R.O., Proton and deuteron radiolysis of argon matrix samples of O2 and Cl2. Infrared spectra of charged species, J. Chem. Phys., 1975, 62, 6, 2461, https://doi.org/10.1063/1.430723 . [all data]

Wight, Ault, et al., 1976
Wight, C.A.; Ault, B.S.; Andrews, L., On microwave discharge sources of new chemical species for matrix-isolation spectroscopy and the identification of charged species, J. Chem. Phys., 1976, 65, 4, 1244, https://doi.org/10.1063/1.433233 . [all data]

Jacox and Milligan, 1972
Jacox, M.E.; Milligan, D.E., Vibrational and electronic spectra of the O3- anion isolated in an argon matrix, J. Mol. Spectrosc., 1972, 43, 1, 148, https://doi.org/10.1016/0022-2852(72)90167-1 . [all data]

Jacox and Milligan, 1972, 2
Jacox, M.E.; Milligan, D.E., Spectrum and structure of the O-3 and O-4 anions isolated in an argon matrix, Chem. Phys. Lett., 1972, 14, 4, 518, https://doi.org/10.1016/0009-2614(72)80253-7 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References