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Dinitrogen pentoxide


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 23800 T gas Harwood, Jones, et al., 1993
Harwood, Burkholder, et al., 1998

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a 1 NO2 a-stretch 1720 vs gas IR Fateley, Bent, et al., 1959
Hisatsune, Devlin, et al., 1962
Lovejoy, Chackerian, et al., 1980
Cantrell, Davidson, et al., 1988
1 NO2 a-stretch 1742.4 vs Ar IR Bencivenni, Sanna, et al., 1996
1 NO2 a-stretch 1745 N2 IR Varetti and Pimentel, 1971
1 NO2 a-stretch 1752 CO2 IR Fateley, Bent, et al., 1959
2 NO2 s-stretch 1338 m gas IR Hisatsune, Devlin, et al., 1962
Cantrell, Davidson, et al., 1988
2 NO2 s-stretch 1339.8 w m Ar IR Bencivenni, Sanna, et al., 1996
2 NO2 s-stretch 1305 N2 IR Varetti and Pimentel, 1971
2 NO2 s-stretch 1300 O2 IR Smith and Guillory, 1977
2 NO2 s-stretch 1316 CO2 IR Fateley, Bent, et al., 1959
3 860 m gas IR Hisatsune, Devlin, et al., 1962
Cantrell, Davidson, et al., 1988
3 863.1 w Ar IR Bencivenni, Sanna, et al., 1996
b 9 NO2 a-stretch 1720 vs gas IR Fateley, Bent, et al., 1959
Hisatsune, Devlin, et al., 1962
Lovejoy, Chackerian, et al., 1980
Cantrell, Davidson, et al., 1988
9 NO2 a-stretch 1702.7 Ar IR Bandow, Akimoto, et al., 1984
Bencivenni, Sanna, et al., 1996
9 NO2 a-stretch 1704 N2 IR Varetti and Pimentel, 1971
9 NO2 a-stretch 1704 O2 IR Smith and Guillory, 1977
9 NO2 a-stretch 1700 CO2 IR Fateley, Bent, et al., 1959
10 NO2 s-stretch 1245.9 s gas IR DL Fateley, Bent, et al., 1959
Hisatsune, Devlin, et al., 1962
Lovejoy, Chackerian, et al., 1980
Cantrell, Davidson, et al., 1988
Harwood, Jones, et al., 1993
Domenech, Fraser, et al., 1997
10 NO2 s-stretch 1243.0 m Ar IR Bandow, Akimoto, et al., 1984
Bencivenni, Sanna, et al., 1996
10 NO2 s-stretch 1247 N2 IR Varetti and Pimentel, 1971
10 NO2 s-stretch 1241 O2 IR Smith and Guillory, 1977
10 NO2 s-stretch 1248 CO2 IR Fateley, Bent, et al., 1959
11 743.4 s gas IR Fateley, Bent, et al., 1959
Hisatsune, Devlin, et al., 1962
Lovejoy, Chackerian, et al., 1980
Cantrell, Davidson, et al., 1988
Harwood, Jones, et al., 1993
11 737 s Ar IR Bandow, Akimoto, et al., 1984
Bencivenni, Sanna, et al., 1996
11 739 N2 IR Varetti and Pimentel, 1971
11 736 O2 IR Smith and Guillory, 1977
11 719 CO2 IR Fateley, Bent, et al., 1959
12 614 m T gas IR Hisatsune, Devlin, et al., 1962
12 639.7 w Ar IR Bencivenni, Sanna, et al., 1996
13 557 s gas IR Hisatsune, Devlin, et al., 1962
Lovejoy, Chackerian, et al., 1980
13 569.4 m Ar IR Bencivenni, Sanna, et al., 1996
14 353 vs T gas IR Hisatsune, Devlin, et al., 1962
De Lucia, Winnewisser, et al., 1989
14 343.9 vs Ar IR Bencivenni, Sanna, et al., 1996
15 50 w b T gas IR De Lucia, Winnewisser, et al., 1989

Additional references: Jacox, 1994, page 370; Jacox, 1998, page 331; Jacox, 2003, page 347; McClelland, Hedberg, et al., 1983; Colmont, 1992; Grabow, Andrews, et al., 1996

Notes

wWeak
mMedium
sStrong
vsVery strong
TTentative assignment or approximate value
dPhotodissociation threshold
bBroad

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Harwood, Jones, et al., 1993
Harwood, M.H.; Jones, R.L.; Cox, R.A.; Lutman, E.; Rattigan, O.V., Temperature-dependent absorption cross-sections of N2O5, J. Photochem. Photobiol. A: Chem., 1993, 73, 3, 167, https://doi.org/10.1016/1010-6030(93)90001-2 . [all data]

Harwood, Burkholder, et al., 1998
Harwood, M.H.; Burkholder, J.B.; Ravishankara, A.R., Photodissociation of BrONO, J. Phys. Chem. A, 1998, 102, 8, 1309, https://doi.org/10.1021/jp9729829 . [all data]

Fateley, Bent, et al., 1959
Fateley, W.G.; Bent, H.A.; Crawford, B., Jr., Infrared Spectra of the Frozen Oxides of Nitrogen, J. Chem. Phys., 1959, 31, 1, 204, https://doi.org/10.1063/1.1730296 . [all data]

Hisatsune, Devlin, et al., 1962
Hisatsune, I.C.; Devlin, J.P.; Wada, Y., Spectrochim. Acta, 1962, 18, 1641. [all data]

Lovejoy, Chackerian, et al., 1980
Lovejoy, R.W.; Chackerian, C., Jr.; Boese, R.W., Integrated band intensities of gaseous N_2O_5, Appl. Opt., 1980, 19, 5, 744, https://doi.org/10.1364/AO.19.000744 . [all data]

Cantrell, Davidson, et al., 1988
Cantrell, C.A.; Davidson, J.A.; McDaniel, A.H.; Shetter, R.E.; Calvert, J.G., Infrared absorption cross sections for N2O5, Chem. Phys. Lett., 1988, 148, 4, 358, https://doi.org/10.1016/0009-2614(88)87288-9 . [all data]

Bencivenni, Sanna, et al., 1996
Bencivenni, L.; Sanna, N.; Schriver-Mazzuoli, L.; Schriver, A., Infrared spectrum and theoretical study of the dinitrogen pentoxide molecule (N2O5) in solid argon, J. Chem. Phys., 1996, 104, 20, 7836, https://doi.org/10.1063/1.471500 . [all data]

Varetti and Pimentel, 1971
Varetti, E.L.; Pimentel, G.C., Isomeric Forms of Dinitrogen Trioxide in a Nitrogen Matrix, J. Chem. Phys., 1971, 55, 8, 3813, https://doi.org/10.1063/1.1676666 . [all data]

Smith and Guillory, 1977
Smith, G.R.; Guillory, W.A., Spectroscopy of the thermal oxidation of NO in solid oxygen at cryogenic temperatures, J. Mol. Spectrosc., 1977, 68, 2, 223, https://doi.org/10.1016/0022-2852(77)90438-6 . [all data]

Bandow, Akimoto, et al., 1984
Bandow, H.; Akimoto, H.; Akiyama, S.; Tezuka, T., Photolysis of asym-N2O4 (ONONO2) isolated in an argon matrix at 11 K, Chem. Phys. Lett., 1984, 111, 4-5, 496, https://doi.org/10.1016/0009-2614(84)85547-5 . [all data]

Domenech, Fraser, et al., 1997
Domenech, J.L.; Fraser, G.T.; Hight Walker, A.R.; Lafferty, W.J.; Suenram, R.D., Infrared and Microwave Molecular-Beam Studies of N2O5, J. Mol. Spectrosc., 1997, 184, 1, 172, https://doi.org/10.1006/jmsp.1997.7323 . [all data]

De Lucia, Winnewisser, et al., 1989
De Lucia, F.C.; Winnewisser, B.P.; Winnewisser, M.; Pawelke, G., The far-infrared spectrum of N2O5 in the gas phase, J. Mol. Spectrosc., 1989, 136, 1, 151, https://doi.org/10.1016/0022-2852(89)90227-0 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

McClelland, Hedberg, et al., 1983
McClelland, B.W.; Hedberg, L.; Hedberg, K.; Hagen, K., Molecular structure of dinitrogen pentoxide in the gas phase. Large amplitude motion in a system of coupled rotors, J. Am. Chem. Soc., 1983, 105, 12, 3789, https://doi.org/10.1021/ja00350a006 . [all data]

Colmont, 1992
Colmont, J.-M., Microwave spectrum of dinitrogen pentoxide, J. Mol. Spectrosc., 1992, 155, 1, 11, https://doi.org/10.1016/0022-2852(92)90544-X . [all data]

Grabow, Andrews, et al., 1996
Grabow, J.-U.; Andrews, A.M.; Fraser, G.T.; Irikura, K.K.; Suenram, R.D.; Lovas, F.J.; Lafferty, W.J.; Domenech, J.L., Microwave spectrum, large-amplitude motions, and ab initio calculations for N2O5, J. Chem. Phys., 1996, 105, 17, 7249, https://doi.org/10.1063/1.472586 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References