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H2O..I anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-112.9 ± 1.0kcal/molTherCaldwell and Kebarle, 1984 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.4499 ± 0.0012ZEKESchlicht, Entfellner, et al., 2010 
3.480 ± 0.040N/APiani, Becucci, et al., 2008Stated electron affinity is the Vertical Detachment Energy
3.500 ± 0.040N/ABowen, Becucci, et al., 2005 
3.44675 ± 0.00013ZEKEBassman, Boesl, et al., 1996 
3.510 ± 0.020LPDMarkovich, Giniger, et al., 1991For photodissociation of bond plus electron loss, agrees with thermo threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Caldwell and Kebarle, 1984
Caldwell, G.; Kebarle, P., Binding energies and structural effects in halide anion-ROH and -RCOOH complexes from gas phase equilibria measurements, J. Am. Chem. Soc., 1984, 106, 967. [all data]

Schlicht, Entfellner, et al., 2010
Schlicht, F.; Entfellner, M.; Boesl, U., Anion ZEKE-Spectroscopy of the Weakly Bound Iodine Water Complex, J. Phys. Chem. A, 2010, 114, 42, 11125-11132, https://doi.org/10.1021/jp102508f . [all data]

Piani, Becucci, et al., 2008
Piani, G.; Becucci, M.; Bowen, M.S.; Oakman, J.; Hu, Q.; Continetti, R.E., Photodetachment and dissociation dynamics of microsolvated iodide clusters, Phys. Scripta, 2008, 78, 5, 058110, https://doi.org/10.1088/0031-8949/78/05/058110 . [all data]

Bowen, Becucci, et al., 2005
Bowen, M.S.; Becucci, M.; Continetti, R.E., Dissociative photodetachment dynamics of solvated iodine cluster anions, J. Phys. Chem. A, 2005, 109, 51, 11781-11792, https://doi.org/10.1021/jp0547358 . [all data]

Bassman, Boesl, et al., 1996
Bassman, C.; Boesl, U.; Yang, D.; Drechsler, G.; Schlag, E.W., Mass-selective Anion ZEKE Spectroscopy of the Iodine-Water Cluster, Int. J. Mass Spectrom. Ion Proc., 1996, 159, 1-3, 153, https://doi.org/10.1016/S0168-1176(96)04448-5 . [all data]

Markovich, Giniger, et al., 1991
Markovich, G.; Giniger, R.; Levin, M.; Cheshnovsky, O., Photoelectron Spectroscopy of Iodine Anion Solvated in Water Clusters, J. Chem. Phys., 1991, 95, 12, 9416, https://doi.org/10.1063/1.461172 . [all data]


Notes

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