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Propynylidene


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 31750 Ar B-X 210 260 Maier, Reisenauer, et al., 1987
Seburg, DePinto, et al., 1995
Seburg and McMahon, 1995
Seburg, Pattersosn, et al., 1997
Seburg, Patterson, et al., 2009

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

gas 310 370 Merer, 1967

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' CH stretch 3266.0 s Ar IR Maier, Reisenauer, et al., 1987
Maier, Reisenauer, et al., 1989
Huang and Graham, 1990
Seburg, DePinto, et al., 1995
Seburg and McMahon, 1995
CH stretch 3285 Kr IR Chi, 1972
C3 a-stretch 1619.4 w Ar IR Maier, Reisenauer, et al., 1989
Huang and Graham, 1990
Seburg, DePinto, et al., 1995
CCH s-bend 550.4 m Ar IR Maier, Reisenauer, et al., 1989
Seburg, DePinto, et al., 1995
402.6 Ar IR Jacox and Milligan, 1974
Maier, Reisenauer, et al., 1987
Maier, Reisenauer, et al., 1989
Huang and Graham, 1990
Seburg, DePinto, et al., 1995
401.5 w m Ar IR Jacox and Milligan, 1974
Maier, Reisenauer, et al., 1987
Maier, Reisenauer, et al., 1989
Huang and Graham, 1990
Seburg, DePinto, et al., 1995
408 Kr IR Chi, 1972
a 7 HCC wag 248.5 Ar IR Jacox and Milligan, 1974
Maier, Reisenauer, et al., 1987
Maier, Reisenauer, et al., 1989
Huang and Graham, 1990
Seburg, DePinto, et al., 1995
7 HCC wag 245.9 s Ar IR Jacox and Milligan, 1974
Maier, Reisenauer, et al., 1987
Maier, Reisenauer, et al., 1989
Huang and Graham, 1990
Seburg, DePinto, et al., 1995
7 HCC deform. 258 Kr IR Chi, 1972

Additional references: Jacox, 1994, page 249; Jacox, 1998, page 278; Bernheim, Kempf, et al., 1965

Notes

wWeak
mMedium
sStrong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Reisenauer, et al., 1987
Maier, G.; Reisenauer, H.P.; Schwab, W.; Carsky, P.; Hess, B.A., Jr.; Schaad, L.J., Vinylidene carbene: a new C3H2 species, J. Am. Chem. Soc., 1987, 109, 17, 5183, https://doi.org/10.1021/ja00251a023 . [all data]

Seburg, DePinto, et al., 1995
Seburg, R.A.; DePinto, J.T.; Patterson, E.V.; McMahon, R.J., Structure of Triplet Propynylidene, J. Am. Chem. Soc., 1995, 117, 2, 835, https://doi.org/10.1021/ja00107a035 . [all data]

Seburg and McMahon, 1995
Seburg, R.A.; McMahon, R.J., Auto- und Isomerisierungen im System Propinyliden (HCCCH), Propadienyliden (H2CCC) und Cyclopropenyliden (c-C3H2), Angew. Chem., 1995, 107, 18, 2198, https://doi.org/10.1002/ange.19951071826 . [all data]

Seburg, Pattersosn, et al., 1997
Seburg, R.A.; Pattersosn, E.V.; Stanton, J.F.; McMahon, R.J., Structures, Automerizations, and Isomerizations of C, J. Am. Chem. Soc., 1997, 119, 25, 5847, https://doi.org/10.1021/ja9638869 . [all data]

Seburg, Patterson, et al., 2009
Seburg, R.A.; Patterson, E.V.; McMahon, R.J., Structure of Triplet Propynylidene (HCCCH) as Probed by IR, UV/vis, and EPR Spectroscopy of Isotopomers, J. Am. Chem. Soc., 2009, 131, 26, 9442, https://doi.org/10.1021/ja901606a . [all data]

Merer, 1967
Merer, A.J., ABSORPTION SPECTRA OF C, Can. J. Phys., 1967, 45, 12, 4103, https://doi.org/10.1139/p67-342 . [all data]

Maier, Reisenauer, et al., 1989
Maier, G.; Reisenauer, H.P.; Schwab, W.; Carsky, P.; Spirko, V.; Hess, B.A., Jr.; Schaad, L.J., Propargylene: A C3H2 isomer with unusual bonding, J. Chem. Phys., 1989, 91, 8, 4763, https://doi.org/10.1063/1.456765 . [all data]

Huang and Graham, 1990
Huang, J.W.; Graham, W.R.M., Fourier transform infrared study of tricarbon hydride radicals trapped in Ar at 10 K, J. Chem. Phys., 1990, 93, 3, 1583, https://doi.org/10.1063/1.459137 . [all data]

Chi, 1972
Chi, F.K., Ph.D. thesis, 1972, Michigan State University. [all data]

Jacox and Milligan, 1974
Jacox, M.E.; Milligan, D.E., Matrix isolation study of the vacuum ultraviolet photolysis of allene and methylacetylene. Vibrational and electronic spectra of the species C3, C3H, C3H2, and C3H3, Chem. Phys., 1974, 4, 1, 45, https://doi.org/10.1016/0301-0104(74)80047-9 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Bernheim, Kempf, et al., 1965
Bernheim, R.A.; Kempf, R.J.; Gramas, J.V.; Skell, P.S., Electron Paramagnetic Resonance of Triplet Alternant Methylenes. Propargylene and Homologs, J. Chem. Phys., 1965, 43, 1, 196, https://doi.org/10.1063/1.1696454 . [all data]


Notes

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