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Ethyl acetoacetate

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltafgas-586.2 ± 1.5kJ/molCcbRibeiro da Silva, Ferrao, et al., 1995ALS
Deltafgas-558.0kJ/molN/AVilcu and Perisanu, 1979Value computed using «DELTA»fHliquid° value of -612.2±5.4 kj/mol from Vilcu and Perisanu, 1979 and «DELTA»vapH° value of 54.2 kj/mol from Ribeiro da Silva, Ferrao, et al., 1995.; DRB
Deltafgas-507.5kJ/molN/AVilcu, Perisanu, et al., 1975Value computed using «DELTA»fHliquid° value of -561.7 kj/mol from Vilcu, Perisanu, et al., 1975 and «DELTA»vapH° value of 54.2 kj/mol from Ribeiro da Silva, Ferrao, et al., 1995.; DRB

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-640.4 ± 1.1kJ/molCcbRibeiro da Silva, Ferrao, et al., 1995ALS
Deltafliquid-612.2 ± 5.4kJ/molCcbVilcu and Perisanu, 1979ALS
Deltafliquid-561.70kJ/molCcbVilcu, Perisanu, et al., 1975ALS
Quantity Value Units Method Reference Comment
Deltacliquid-3149.76 ± 0.76kJ/molCcbRibeiro da Silva, Ferrao, et al., 1995Corresponding «DELTA»fliquid = -640.45 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3178.1 ± 7.7kJ/molCcbVilcu and Perisanu, 1979Corresponding «DELTA»fliquid = -612.08 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3153.kJ/molCcbGuinchant, 1918Corresponding «DELTA»fliquid = -637.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
250.2297.5Kolosovskii and Udovenko, 1934DH
246.9297.5de Kolossowsky and Udowenko, 1933DH
241.8298.von Reis, 1881T = 288 to 455 K.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Ferrao, et al., 1995
Ribeiro da Silva, M.A.V.; Ferrao, M.L.C.C.H.; Jiye, F., Standard molar enthalpy of formation and of vaporization of ethyl 3-oxobutanoate, J. Chem. Eng. Data, 1995, 40, 426-428. [all data]

Vilcu and Perisanu, 1979
Vilcu, R.; Perisanu, S., The standard enthalpies of formation of some C, H, O containing compounds, Rev. Roum. Chim., 1979, 24, 237-243. [all data]

Vilcu, Perisanu, et al., 1975
Vilcu, R.; Perisanu, S.; Ciocazanu, I., Heats of formation in the ideal gas state of some substances containing carbon, hydrogen and oxygen, Conf. Int. Thermodyn. Chim. C.R. 4th, 1975, 1, 105-112. [all data]

Guinchant, 1918
Guinchant, M.J., Etude sur la fonction acide dans les derives metheniques et methiniques, Ann. Chem., 1918, 10, 30-84. [all data]

Kolosovskii and Udovenko, 1934
Kolosovskii, N.A.; Udovenko, W.W., Specific heat of liquids. II., Zhur. Obshchei Khim., 1934, 4, 1027-1033. [all data]

de Kolossowsky and Udowenko, 1933
de Kolossowsky, N.A.; Udowenko, W.W., Mesure des chaleurs specifique moleculaires de quelques liquides, Compt. rend., 1933, 197, 519-520. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


Notes

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