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ClClO


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 38500 Ar Johnsson, Engdahl, et al., 1995
Johnsson, Engdahl, et al., 1995, 2

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 ClO stretch 961.6 s Ar IR Ra Chi and Andrews, 1973
Schriver-Mazzuoli, Abdelaoui, et al., 1993
Johnsson, Engdahl, et al., 1995
Johnsson, Engdahl, et al., 1995, 2
1 ClO stretch 963 N2 IR Rochkind and Pimentel, 1967
Alcock and Pimentel, 1968
2 Bend 240.2 w m Ar IR Ra Chi and Andrews, 1973
Johnsson, Engdahl, et al., 1995
Johnsson, Engdahl, et al., 1995, 2
3 ClCl stretch 374.2 m s Ar IR Ra Chi and Andrews, 1973
Johnsson, Engdahl, et al., 1995
Johnsson, Engdahl, et al., 1995, 2
3 ClCl stretch 377 N2 IR Rochkind and Pimentel, 1967
Alcock and Pimentel, 1968

Additional references: Jacox, 1994, page 116; Jacox, 1998, page 208

Notes

wWeak
mMedium
sStrong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Johnsson, Engdahl, et al., 1995
Johnsson, K.; Engdahl, A.; Nelander, B., The UV and IR Spectra of the ClClO Molecule, J. Phys. Chem., 1995, 99, 12, 3965, https://doi.org/10.1021/j100012a016 . [all data]

Johnsson, Engdahl, et al., 1995, 2
Johnsson, K.; Engdahl, A.; Nelander, B., The UV and IR intensities of the ClClO molecule, J. Mol. Struct., 1995, 348, 195, https://doi.org/10.1016/0022-2860(95)08622-3 . [all data]

Chi and Andrews, 1973
Chi, F.K.; Andrews, L., Argon matrix Raman spectra of dichlorine monoxide and its photolysis products monochlorine monoxide and chlorine-monochlorine monoxide. Infrared matrix spectra of monochlorine monoxide and dimeric monochlorine monoxide, J. Phys. Chem., 1973, 77, 26, 3062, https://doi.org/10.1021/j100644a007 . [all data]

Schriver-Mazzuoli, Abdelaoui, et al., 1993
Schriver-Mazzuoli, L.; Abdelaoui, O.; Lugez, C.; Schriver, A., Matrix reaction of ozone with Cl2 and Br2. FTIR identification of BrC10 and ClBrO species, Chem. Phys. Lett., 1993, 214, 5, 519, https://doi.org/10.1016/0009-2614(93)85676-F . [all data]

Rochkind and Pimentel, 1967
Rochkind, M.M.; Pimentel, G.C., Photolysis of Matrix-Isolated Dichlorine Monoxide: Infrared Spectra of ClClO and (ClO)2, J. Chem. Phys., 1967, 46, 11, 4481, https://doi.org/10.1063/1.1840572 . [all data]

Alcock and Pimentel, 1968
Alcock, W.G.; Pimentel, G.C., Infrared Spectrum of Dichlorine Dioxide (ClO)2, J. Chem. Phys., 1968, 48, 5, 2373, https://doi.org/10.1063/1.1669442 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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