Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

SF6+


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 94450 ± 100 gas Potts, Lempka, et al., 1970
Karlsson, Mattsson, et al., 1976
Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 690 ± 40 gas PE Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997
eg 2 460 T gas PE TPE Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 57620 ± 100 gas Potts, Lempka, et al., 1970
Karlsson, Mattsson, et al., 1976
Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 1 Sym. stretch 540 ± 40 gas PE TPE Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 33250 ± 150 gas Frost, McDowell, et al., 1967
Potts, Lempka, et al., 1970
Karlsson, Mattsson, et al., 1976
Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 1 Sym. stretch 590 ± 40 gas PE TPE Karlsson, Mattsson, et al., 1976
Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 24360 ± 100 U gas Frost, McDowell, et al., 1967
Potts, Lempka, et al., 1970
Karlsson, Mattsson, et al., 1976
Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997
Yang, Agren, et al., 1998

State:   A,B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 12780 ± 240 gas Frost, McDowell, et al., 1967
Potts, Lempka, et al., 1970
Karlsson, Mattsson, et al., 1976
Holland, MacDonald, et al., 1995
Yencha, Thompson, et al., 1997
Yang, Agren, et al., 1998

Additional references: Jacox, 1998, page 331; Jacox, 2003, page 347; Creasey, Lambert, et al., 1991; Creasey, Jones, et al., 1993

Notes

UUpper bound
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Potts, Lempka, et al., 1970
Potts, A.W.; Lempka, H.J.; Streets, D.G.; Price, W.C., Photoelectron spectra of the halides of elements in groups III, IV, V and VI, Phil. Trans. Roy. Soc. (London), 1970, A268, 59. [all data]

Karlsson, Mattsson, et al., 1976
Karlsson, L.; Mattsson, L.; Jadrny, R.; Bergmark, T.; Siegbahn, K., Valence Electron Spectra of Benzene and the Hexafluorides of Sulphur, Molybdenum, Tungsten and Uranium., Phys. Scripta, 1976, 14, 5, 230, https://doi.org/10.1088/0031-8949/14/5/007 . [all data]

Holland, MacDonald, et al., 1995
Holland, D.M.P.; MacDonald, M.A.; Baltzer, P.; Karlsson, L.; Lundqvist, M.; Wannberg, B.; von Niessen, W., An experimental and theoretical study of the valence shell photoelectron spectrum of sulphur hexafluoride, Chem. Phys., 1995, 192, 3, 333, https://doi.org/10.1016/0301-0104(94)00381-J . [all data]

Yencha, Thompson, et al., 1997
Yencha, A.J.; Thompson, D.B.; Cormack, A.J.; Cooper, D.R.; Zubek, M.; Bolognesi, P.; King, G.C., Threshold photoelectron spectroscopy of SF6, Chem. Phys., 1997, 216, 1-2, 227, https://doi.org/10.1016/S0301-0104(96)00372-2 . [all data]

Frost, McDowell, et al., 1967
Frost, D.C.; McDowell, C.A.; Sandhu, J.S.; Vroom, D.A., Photoelectron spectrum of sulfur hexafluoride at 584 A, J. Chem. Phys., 1967, 46, 2008. [all data]

Yang, Agren, et al., 1998
Yang, L.; Agren, H.; Carravetta, V.; Vahtras, O.; Karlsson, L.; Wannberg, B., et al., Energy-dependent valence photoelectron spectra of SF6. Ab initio calculations and measurements, J. Electron Spectrosc. Relat. Phenom., 1998, 94, 1-2, 163, https://doi.org/10.1016/S0368-2048(98)00085-1 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Creasey, Lambert, et al., 1991
Creasey, J.C.; Lambert, I.R.; Tuckett, R.P.; Codling, K.; Fransinski, L.J.; Hatherly, P.A.; Stankiewicz, M., J. Chem. Soc., 1991, Faraday Trans. 87, 1287. [all data]

Creasey, Jones, et al., 1993
Creasey, J.C.; Jones, H.M.; Smith, D.M.; Tuckett, R.P.; Hatherly, P.A.; Codling, K.; Powis, I., Fragmentation of valence electronic states of CF+4 and SF+6 studied by threshold photoelectron-photoion coincidence spectroscopy, Chem. Phys., 1993, 174, 3, 441, https://doi.org/10.1016/0301-0104(93)80010-7 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References