Difluoromethane

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-450.66kJ/molReviewChase, 1998Data last reviewed in December, 1969
Δfgas-452.21 ± 0.92kJ/molCcrNeugebauer and Margrave, 1958Corrected for CODATA value of ΔfH; ALS
Quantity Value Units Method Reference Comment
Δcgas-583.08kJ/molCcrNeugebauer and Margrave, 1958Corrected for CODATA value of ΔfH; ALS
Quantity Value Units Method Reference Comment
gas,1 bar246.70J/mol*KReviewChase, 1998Data last reviewed in December, 1969

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 298. - 1200.1200. - 6000.
A -6.09868294.67555
B 179.22006.983473
C -122.3682-1.341897
D 32.302070.089387
E 0.491361-18.07061
F -454.1439-519.5482
G 193.7979307.0742
H -450.6586-450.6586
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1969 Data last reviewed in December, 1969

References

Go To: Top, Gas phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Neugebauer and Margrave, 1958
Neugebauer, C.A.; Margrave, J.L., The heats of formation of CHF3 and CH2F2, J. Phys. Chem., 1958, 62, 1043-1048. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, References