Chlorine atom

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 12599-09-6 • 4294967295Chlorine atom) + Chlorine atom = CAS Reg. No. 12599-09-6

By formula: (CAS Reg. No. 12599-09-6 • 4294967295Cl) + Cl = CAS Reg. No. 12599-09-6

Quantity Value Units Method Reference Comment
Δr172. ± 7.1kJ/molCIDTLobring, Check, et al., 2005gas phase; Affinity is Cl.. POCl2-; B

CAS Reg. No. 666718-71-4 + Chlorine atom = Cl2PS-

By formula: CAS Reg. No. 666718-71-4 + Cl = Cl2PS-

Quantity Value Units Method Reference Comment
Δr186. ± 5.9kJ/molCIDTLobring, Check, et al., 2005gas phase; Affinity is Cl.. ClPS-; B

Ethane, 1-chloro-2-iodo- = Iodine atom + Chlorine atom + Ethylene

By formula: C2H4ClI = I + Cl + C2H4

Quantity Value Units Method Reference Comment
Δr320. ± 4.2kJ/molKinMinton, Felder, et al., 1984gas phase; ALS

C4BrClO4Re + Chlorine atom = C4BrClO4Re-

By formula: C4BrClO4Re + Cl = C4BrClO4Re-

Quantity Value Units Method Reference Comment
Δr>331.4kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

C4ClO4Re + Chlorine atom = C4Cl2O4Re-

By formula: C4ClO4Re + Cl = C4Cl2O4Re-

Quantity Value Units Method Reference Comment
Δr>331.4kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

C4BrIMnO4 + Chlorine atom = C4BrClMnO4-

By formula: C4BrIMnO4 + Cl = C4BrClMnO4-

Quantity Value Units Method Reference Comment
Δr>294.1kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

C4ClIMnO4 + Chlorine atom = C4Cl2MnO4-

By formula: C4ClIMnO4 + Cl = C4Cl2MnO4-

Quantity Value Units Method Reference Comment
Δr>294.1kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

C6H5O3Re + Chlorine atom = C6H5ClO3Re-

By formula: C6H5O3Re + Cl = C6H5ClO3Re-

Quantity Value Units Method Reference Comment
Δr>346.4kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

CAS Reg. No. 121175-69-7 + Chlorine atom = C6H5ClMnO3-

By formula: CAS Reg. No. 121175-69-7 + Cl = C6H5ClMnO3-

Quantity Value Units Method Reference Comment
Δr>294.1kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

C5CrO5- + Chlorine atom = C5ClCrO5-

By formula: C5CrO5- + Cl = C5ClCrO5-

Quantity Value Units Method Reference Comment
Δr>331.4kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

C3NiO3- + Chlorine atom = C3ClNiO3-

By formula: C3NiO3- + Cl = C3ClNiO3-

Quantity Value Units Method Reference Comment
Δr>331.4kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

C4FeO4- + Chlorine atom = C4ClFeO4-

By formula: C4FeO4- + Cl = C4ClFeO4-

Quantity Value Units Method Reference Comment
Δr>294.1kJ/molIMRBJones, McDonald, et al., 1989gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lobring, Check, et al., 2005
Lobring, K.C.; Check, C.E.; Boggs, M.L.; Keating, P.R.; Sunderlin, L.S., Bond strengths in POCl3-, POCl2-, and PSCl2-, Int. J. Mass Spectrom., 2005, 241, 1, 75-81, https://doi.org/10.1016/j.ijms.2004.10.023 . [all data]

Minton, Felder, et al., 1984
Minton, T.K.; Felder, P.; Brudzynski, R.J.; Lee, Y.T., Photodissociation of 1,2-chloroiodoethane at 248 and 266 nm: The enthalpy of formation of CH2ClCH2I, J. Chem. Phys., 1984, 81, 1759-1769. [all data]

Jones, McDonald, et al., 1989
Jones, M.T.; McDonald, R.N.; Schell, P.L.; Ali, M.H., Kinetics and Mechanism of Halogen Atom Transfer Reactions between Haloalkanes and Several 17-Electron Transition Metal Complex Negative Ions in the Gas Phase, J. Am. Chem. Soc., 1989, 111, 16, 5983, https://doi.org/10.1021/ja00198a001 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References