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HFCS+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 28720 ± 120 gas Baker, Butcher, et al., 1995


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1210 ± 80 gas PE Baker, Butcher, et al., 1995
980 ± 80 gas PE Baker, Butcher, et al., 1995

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 10810 ± 180 gas Baker, Butcher, et al., 1995


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1450 ± 80 gas PE Baker, Butcher, et al., 1995
750 ± 80 gas PE Baker, Butcher, et al., 1995

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1360 ± 60 gas PE Baker, Butcher, et al., 1995

Additional references: Jacox, 1998, page 237

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baker, Butcher, et al., 1995
Baker, J.; Butcher, V.A.; Dyke, J.M.; Lee, E.P.F., A Study of the Reactions of Molecular Fluorine with CH3SCH3 and CH3SSCH3 with UV Photoelectron Spectroscopy: First Observation of the HFCS Molecule, J. Phys. Chem., 1995, 99, 25, 10147, https://doi.org/10.1021/j100025a015 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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