Copper, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-

• Formula: C₁₀H₁₄CuO₄
• Molecular weight: 261.762
• IUPAC Standard InChI: InChI=1S/2C5H8O2.Cu/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-; Copy

  
• IUPAC Standard InChIKey: QYJPSWYYEKYVEJ-FDGPNNRMSA-L Copy
• CAS Registry Number: 13395-16-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Species with the same structure:
  • Copper, bis(2,4-pentanedionato-O,O')-
• Other names: Bis(acetylacetonato)copper; Copper, bis(2,4-pentanedionato)-; Bis(2,4-pentanedionato)copper; Copper acetylacetonate; Copper bis(acetylacetonate); Copper diacetylacetonate; Copper(II) acetylacetonate; Cupric acetylacetonate; CD 9; Copper(II) 2,4-pentanedionate; Copper bis(2,4-pentanedionate); Copper, bis(2,4-pentanedionato-O,O')-; CD 9Thimet G; copper(II) 4-oxopent-2-en-2-olate
• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Siddiqi, Siddiqui, et al., 2009
Siddiqi, M. Aslam; Siddiqui, Rehan A.; Atakan, Burak, Thermal Stability, Sublimation Pressures, and Diffusion Coefficients of Anthracene, Pyrene, and Some Metal β-Diketonates, J. Chem. Eng. Data, 2009, 54, 10, 2795-2802, https://doi.org/10.1021/je9001653 . [all data]

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

Ribeiro da Silva, 1995
Ribeiro da Silva, M., Vapour pressures and standard molar enthalpies of sublimation of seven crystalline copper(II) β-diketonates. The mean molar (Cu-O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1995, 27, 2, 175-190, https://doi.org/10.1006/jcht.1995.0014 . [all data]

Murray and Hill, 1987
Murray, J.P.; Hill, J.O., DSC determination of the sublimation enthalpy of tris(2,4-pentanedionato)cobalt(III) and bis(2,4-pentanedionato) nickel(II) and -copper(II), Thermochimica Acta, 1987, 109, 2, 383-390, https://doi.org/10.1016/0040-6031(87)80034-5 . [all data]

Ribeiro Da Silva and Ferrão, 1987
Ribeiro Da Silva, Manuel A.V.; Ferrão, Maria Luísa C.C.H., Standard enthalpies of formation of tris(β-diketonate)chromium(III) complexes: the mean (Cr«58872»O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1987, 19, 6, 645-652, https://doi.org/10.1016/0021-9614(87)90070-X . [all data]

Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H., Dampfdruckbestimmung von Acetylacetonaten, Zeitschrift für Physikalische Chemie, 1970, 73, 4₆, 314-320, https://doi.org/10.1524/zpch.1970.73.4₆.314 . [all data]

Notes

Go To: Top, Phase change data, References

• Symbols used in this document:
  

  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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