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H3S+


Reaction thermochemistry data

Go To: Top, Ion clustering data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

H3S+ + Hydrogen sulfide = (H3S+ bullet Hydrogen sulfide)

By formula: H3S+ + H2S = (H3S+ bullet H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar64.4kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Deltar45.2kJ/molPIWalters and Blais, 1984gas phase
Deltar44.4kJ/molPIPrest, Tzeng, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase
Deltar74.5J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable
Deltar78.2J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(H3S+ bullet 3Hydrogen sulfide) + Hydrogen sulfide = (H3S+ bullet 4Hydrogen sulfide)

By formula: (H3S+ bullet 3H2S) + H2S = (H3S+ bullet 4H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar28.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Deltar10.kJ/molPIWalters and Blais, 1984gas phase
Deltar14.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase
Deltar42.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable

(H3S+ bullet 2Hydrogen sulfide) + Hydrogen sulfide = (H3S+ bullet 3Hydrogen sulfide)

By formula: (H3S+ bullet 2H2S) + H2S = (H3S+ bullet 3H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molPIWalters and Blais, 1984gas phase
Deltar35.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Deltar23.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase
Deltar59.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable

(H3S+ bullet Hydrogen sulfide) + Water = (H3S+ bullet Water bullet Hydrogen sulfide)

By formula: (H3S+ bullet H2S) + H2O = (H3S+ bullet H2O bullet H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar79.9kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3S+ H2O)H2O; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3S+ H2O)H2O; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984

(H3S+ bullet Hydrogen sulfide) + Hydrogen sulfide = (H3S+ bullet 2Hydrogen sulfide)

By formula: (H3S+ bullet H2S) + H2S = (H3S+ bullet 2H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Deltar25.kJ/molPIWalters and Blais, 1984gas phase
Deltar30.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase
Deltar72.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(H3S+ bullet Water) + Water = (H3S+ bullet 2Water)

By formula: (H3S+ bullet H2O) + H2O = (H3S+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar84.9kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3O+ H2O)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3O+ H2O)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976

H3S+ + Water = (H3S+ bullet Water)

By formula: H3S+ + H2O = (H3S+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar88.7kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976

(H3S+ bullet 4Hydrogen sulfide) + Hydrogen sulfide = (H3S+ bullet 5Hydrogen sulfide)

By formula: (H3S+ bullet 4H2S) + H2S = (H3S+ bullet 5H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar26.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.1185.PHPMSHiraoka and Kebarle, 1977gas phase

H3S+ + Methane = (H3S+ bullet Methane)

By formula: H3S+ + CH4 = (H3S+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molHPMSBennet and Field, 1972gas phase
Quantity Value Units Method Reference Comment
Deltar75.7J/mol*KHPMSBennet and Field, 1972gas phase

(H3S+ bullet 2Water) + Water = (H3S+ bullet 3Water)

By formula: (H3S+ bullet 2H2O) + H2O = (H3S+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molPIWalters and Blais, 1984gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

H3S+ + Methane = (H3S+ bullet Methane)

By formula: H3S+ + CH4 = (H3S+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molHPMSBennet and Field, 1972gas phase
Quantity Value Units Method Reference Comment
Deltar75.7J/mol*KHPMSBennet and Field, 1972gas phase

H3S+ + Water = (H3S+ bullet Water)

By formula: H3S+ + H2O = (H3S+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar88.7kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976

(H3S+ bullet Water) + Water = (H3S+ bullet 2Water)

By formula: (H3S+ bullet H2O) + H2O = (H3S+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar84.9kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3O+ H2O)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3O+ H2O)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976

(H3S+ bullet 2Water) + Water = (H3S+ bullet 3Water)

By formula: (H3S+ bullet 2H2O) + H2O = (H3S+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molPIWalters and Blais, 1984gas phase

H3S+ + Hydrogen sulfide = (H3S+ bullet Hydrogen sulfide)

By formula: H3S+ + H2S = (H3S+ bullet H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar64.4kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Deltar45.2kJ/molPIWalters and Blais, 1984gas phase
Deltar44.4kJ/molPIPrest, Tzeng, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase
Deltar74.5J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable
Deltar78.2J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(H3S+ bullet Hydrogen sulfide) + Water = (H3S+ bullet Water bullet Hydrogen sulfide)

By formula: (H3S+ bullet H2S) + H2O = (H3S+ bullet H2O bullet H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar79.9kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3S+ H2O)H2O; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; From thermochemical cycle,switching reaction(H3S+ H2O)H2O; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984

(H3S+ bullet Hydrogen sulfide) + Hydrogen sulfide = (H3S+ bullet 2Hydrogen sulfide)

By formula: (H3S+ bullet H2S) + H2S = (H3S+ bullet 2H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Deltar25.kJ/molPIWalters and Blais, 1984gas phase
Deltar30.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase
Deltar72.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(H3S+ bullet 2Hydrogen sulfide) + Hydrogen sulfide = (H3S+ bullet 3Hydrogen sulfide)

By formula: (H3S+ bullet 2H2S) + H2S = (H3S+ bullet 3H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molPIWalters and Blais, 1984gas phase
Deltar35.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Deltar23.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase
Deltar59.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable

(H3S+ bullet 3Hydrogen sulfide) + Hydrogen sulfide = (H3S+ bullet 4Hydrogen sulfide)

By formula: (H3S+ bullet 3H2S) + H2S = (H3S+ bullet 4H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar28.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Deltar10.kJ/molPIWalters and Blais, 1984gas phase
Deltar14.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase
Deltar42.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change is questionable

(H3S+ bullet 4Hydrogen sulfide) + Hydrogen sulfide = (H3S+ bullet 5Hydrogen sulfide)

By formula: (H3S+ bullet 4H2S) + H2S = (H3S+ bullet 5H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar26.kJ/molPHPMSHiraoka and Kebarle, 1977gas phase
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.1185.PHPMSHiraoka and Kebarle, 1977gas phase

Vibrational and/or electronic energy levels

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SH stretch 2521.05 gas LD Nakanaga and Amano, 1989
2 Umbrella 1033.31 gas DL Amano, Kawaguchi, et al., 1987
e 3 SH stretch 2525.74 gas LD Nakanaga and Amano, 1987
Nakanaga and Amano, 1989

Additional references: Jacox, 1994, page 130; Jacox, 1998, page 217; Jacox, 2003, page 160; Lee, Ozeki, et al., 1994; Xia, Sanz, et al., 1998; Araki, Ozeki, et al., 1998; Dore, Degli Esposti, et al., 1999


References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Kebarle, 1977
Hiraoka, K.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Proton in Hydrogen Sulfide and Hydrogen Sulfide - Water Mixtures. Stabilities of the Hydrogen Bonded Complexes H+(H2S)x(H2O)y, Can. J. Chem., 1977, 55, 1, 24, https://doi.org/10.1139/v77-005 . [all data]

Walters and Blais, 1984
Walters, E.A.; Blais, N.C., Molecular beam photoionization and fragmentation of D2S, (H2S)2, (D2S)2, and H2S.H2O, J. Chem. Phys., 1984, 80, 3501. [all data]

Prest, Tzeng, et al., 1983
Prest, H.F.; Tzeng, W.-B.; Brom, J.M., Jr.; Ng, C.Y., Photoionization study of (H2S)2 and (H2S)3, J. Am. Chem. Soc., 1983, 105, 7531. [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Stability, Association and Dissociation in the Cluster Ions H3S+.nH2S, H3O+.nH2O and H3O+.H2O, J. Am. Chem. Soc., 1977, 99, 4, 998, https://doi.org/10.1021/ja00446a004 . [all data]

Cunningham, Payzant, et al., 1972
Cunningham, A.J.; Payzant, J.D.; Kebarle, P., A Kinetic Study of the Proton Hydrate H+(H2O)n Equilibria in the Gas Phase, J. Am. Chem. Soc., 1972, 94, 22, 7627, https://doi.org/10.1021/ja00777a003 . [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]

Yamdagni and Kebarle, 1976
Yamdagni, R.; Kebarle, P., Gas Phase Basicities and Proton Affinities of Compounds Between Water Ammonia and Substituted Benzenes from a Continuous Ladder of Proton Transfer Equilibrium Measurements, J. Am. Chem. Soc., 1976, 98, 6, 1320, https://doi.org/10.1021/ja00422a005 . [all data]

Bennet and Field, 1972
Bennet, S.L.; Field, F.H., Reversible Reactions of Gaseous Ions. VI. The NH3 - CH4, H2S - CH4 and CF4 - CH4 Systems at Low Temperatures, J. Am. Chem. Soc., 1972, 94, 18, 6305, https://doi.org/10.1021/ja00773a009 . [all data]

Nakanaga and Amano, 1989
Nakanaga, T.; Amano, T., Difference frequency laser spectroscopy of SH3+: A simultaneous analysis of the «nu»1 and «nu»3 fundamental bands, J. Mol. Spectrosc., 1989, 133, 1, 201, https://doi.org/10.1016/0022-2852(89)90254-3 . [all data]

Amano, Kawaguchi, et al., 1987
Amano, T.; Kawaguchi, K.; Hirota, E., Infrared diode laser spectroscopy of the «nu»2 fundamental band of SH3+, J. Mol. Spectrosc., 1987, 126, 1, 177, https://doi.org/10.1016/0022-2852(87)90088-9 . [all data]

Nakanaga and Amano, 1987
Nakanaga, T.; Amano, T., The observation of the high-resolution infrared spectrum of SH+3, Chem. Phys. Lett., 1987, 134, 2, 195, https://doi.org/10.1016/0009-2614(87)87120-8 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Lee, Ozeki, et al., 1994
Lee, S.K.; Ozeki, H.; Saito, S.; Yamamoto, S., Submillimeter wave spectrum of the SH+3 ion. J = 2-1, K = 0 and 1 transitions, Chem. Phys. Lett., 1994, 224, 1-2, 21, https://doi.org/10.1016/0009-2614(94)00519-2 . [all data]

Xia, Sanz, et al., 1998
Xia, C.; Sanz, M.M.; Foster, S.C., Diode Laser Spectroscopy of the «nu»1and «nu»3Bands of SD+3, J. Mol. Spectrosc., 1998, 188, 2, 175, https://doi.org/10.1006/jmsp.1997.7513 . [all data]

Araki, Ozeki, et al., 1998
Araki, M.; Ozeki, H.; Saito, S., Microwave Spectrum of the SD+3Ion: Molecular Structure, J. Mol. Spectrosc., 1998, 192, 1, 228, https://doi.org/10.1006/jmsp.1998.7691 . [all data]

Dore, Degli Esposti, et al., 1999
Dore, L.; Degli Esposti, C.; Mazzavillani, A.; Cazzoli, G., Pure rotational spectra of and, Chem. Phys. Lett., 1999, 300, 3-4, 489, https://doi.org/10.1016/S0009-2614(98)01403-1 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References