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C13


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   1Su+


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 26341 ± 15 Ne 1Su+-X 370 380 Forney, Freivogel, et al., 1996
To = 24969 Ar Szczepanski, Fuller, et al., 2001


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

669 ± 20 Ne AB Forney, Freivogel, et al., 1996
424 ± 20 Ne AB Forney, Freivogel, et al., 1996
207 ± 20 Ne AB Forney, Freivogel, et al., 1996

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 18761 ± 7 Ne Forney, Freivogel, et al., 1996


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 2409 ± 10 Ne AB Forney, Freivogel, et al., 1996
2 2258 ± 10 Ne AB Forney, Freivogel, et al., 1996
6 307 ± 10 Ne AB Forney, Freivogel, et al., 1996

State:   a


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 7750 ± 80 gas Kohno, Suzuki, et al., 1999

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmau+ 1808.96 gas DL Giesen, Van Orden, et al., 1994

Additional references: Jacox, 1998, page 356; Jacox, 2003, page 381

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Forney, Freivogel, et al., 1996
Forney, D.; Freivogel, P.; Grutter, M.; Maier, J.P., Electronic absorption spectra of linear carbon chains in neon matrices. IV. C2n+1 n=2--7, J. Chem. Phys., 1996, 104, 13, 4954, https://doi.org/10.1063/1.471127 . [all data]

Szczepanski, Fuller, et al., 2001
Szczepanski, J.; Fuller, J.; Ekern, S.; Vala, M., Electronic absorption and resonance Raman spectra of large linear carbon clusters isolated in solid argon, Spectrochim. Acta A, 2001, 57, 4, 775, https://doi.org/10.1016/S1386-1425(00)00443-1 . [all data]

Kohno, Suzuki, et al., 1999
Kohno, M.; Suzuki, S.; Shiromaru, H.; Achiba, Y., Characterization of the lowest triplet states of linear form C[sub 2n+1] by anion photoelectron spectroscopy, J. Chem. Phys., 1999, 110, 8, 3781, https://doi.org/10.1063/1.478269 . [all data]

Giesen, Van Orden, et al., 1994
Giesen, T.F.; Van Orden, A.; Hwang, H.J.; Fellers, R.S.; Provencal, R.A.; Saykally, R.J., Infrared laser spectroscopy of the linear C13 carbon cluster, Science, 1994, 265, 5173, 756, https://doi.org/10.1126/science.11539187 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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