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Fluorine nitrate

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas10.46kJ/molReviewChase, 1998Data last reviewed in March, 1963
Quantity Value Units Method Reference Comment
gas,1 bar292.93J/mol*KReviewChase, 1998Data last reviewed in March, 1963

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1100.1100. - 6000.
A 31.64016106.1380
B 160.55641.081908
C -133.7537-0.217921
D 40.671790.015041
E -0.310670-8.304028
F -6.052282-43.14792
G 287.1847389.4522
H 10.4600010.46000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in March, 1963 Data last reviewed in March, 1963

Phase change data

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Quantity Value Units Method Reference Comment
Tboil231.KN/AYost and Beerbower, 1935Uncertainty assigned by TRC = 4. K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NO2 a-stretch 1760.9 vs gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
1 NO2 a-stretch 1758.4 Ne IR Casper, Dixon, et al., 1994
2 NO2 s-stretch 1301.2 vs gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
2 NO2 s-stretch 1300.9 Ne IR Casper, Dixon, et al., 1994
3 OF stretch 927 m gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
3 OF stretch 929.8 Ne IR Casper, Dixon, et al., 1994
4 NO2 scissors 803.4 s gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
4 NO2 scissors 802.7 Ne IR Casper, Dixon, et al., 1994
5 O-N stretch 632.9 w gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
5 O-N stretch 635.0 Ne IR Casper, Dixon, et al., 1994
6 NO2 rock 458.5 m s gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
6 NO2 rock 459.9 Ne IR Casper, Dixon, et al., 1994
7 OF rock 302.6 w gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
7 OF rock 300.0 Ne IR Casper, Dixon, et al., 1994
a 8 NO2 wag 707.3 m gas IR Miller, Bernitt, et al., 1967
Casper, Dixon, et al., 1994
8 NO2 wag 710.0 Ne IR Casper, Dixon, et al., 1994
9 Torsion 151.6 w gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
9 Torsion 161.0 Ne IR Casper, Dixon, et al., 1994

Additional references: Jacox, 1998, page 302

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Yost and Beerbower, 1935
Yost, D.M.; Beerbower, A., The Reaction of Cluorine with Nitric Acid and With Solid Potassium Nitrate to Form NO3F, J. Am. Chem. Soc., 1935, 57, 782. [all data]

Arvia, Cafferata, et al., 1963
Arvia, A.J.; Cafferata, L.F.R.; Schumacher, H.J., Das Infrarotspektrum und die Struktur von NO3Cl und NO3F, Chem. Ber., 1963, 96, 5, 1187, https://doi.org/10.1002/cber.19630960502 . [all data]

Miller, Bernitt, et al., 1967
Miller, R.H.; Bernitt, D.L.; Hisatsune, I.C., Spectrochim. Acta, 1967, 23A, 223. [all data]

Shamir, Yellin, et al., 1974
Shamir, J.; Yellin, D.; Claassen, H.H., Isr. J. Chem., 1974, 12, 1015. [all data]

Casper, Dixon, et al., 1994
Casper, B.; Dixon, D.A.; Mack, H.-G.; Ulic, S.E.; Willner, H.; Oberhammer, H., Molecular Structure of Fluorine Nitrate: Dangerous for Experiment and Theory, J. Am. Chem. Soc., 1994, 116, 18, 8317, https://doi.org/10.1021/ja00097a044 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Vibrational and/or electronic energy levels, References