PCl2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E (4p)
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 51320 ± 10 gas Brum and Hudgens, 1994
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 600 ± 15 gas MPI Brum and Hudgens, 1994
2 Bend 240 ± 15 gas MPI Brum and Hudgens, 1994

State:   D (4s)
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 42760 ± 15 gas Brum and Hudgens, 1994
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 620 ± 20 gas MPI Brum and Hudgens, 1994
2 Bend 230 ± 20 gas MPI Brum and Hudgens, 1994

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 21740 gas B-X Bramwell, Jaeger, et al., 1992
Boyle, Jarvis, et al., 1998

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 452 Ar IR Andrews and Frederick, 1969
b2 3 Asym. stretch 525 Ar IR Andrews and Frederick, 1969

Additional references: Jacox, 1994, page 108; Jacox, 1998, page 203; Jacox, 2003, page 147

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brum and Hudgens, 1994
Brum, J.L.; Hudgens, J.W., Multiphoton Ionization Spectroscopy of PCl2 Radicals: Observation of Two New Rydberg States, J. Phys. Chem., 1994, 98, 22, 5587, https://doi.org/10.1021/j100073a001 . [all data]

Bramwell, Jaeger, et al., 1992
Bramwell, M.J.; Jaeger, S.E.; Whitehead, J.C., The 193 nm photolysis of phosphorus trichloride and phosphorus tribromide, Chem. Phys. Lett., 1992, 196, 6, 547, https://doi.org/10.1016/0009-2614(92)85991-I . [all data]

Boyle, Jarvis, et al., 1998
Boyle, K.J.; Jarvis, G.K.; Tuckett, R.P.; Baumgartel, H.; Jochims, H.-W., J. Chem. Soc., 1998, Faraday Trans. 94, 2073. [all data]

Andrews and Frederick, 1969
Andrews, L.; Frederick, D.L., Infrared spectra of the dichloro- and dibromophosphinyl radicals in solid argon, J. Phys. Chem., 1969, 73, 8, 2774, https://doi.org/10.1021/j100842a054 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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