C5S

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   1S+
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 35169 ± 25 Ne 1S+-X 244 285 Riaplov and Maier, 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 2 CC stretch 1734 ± 35 Ne AB Riaplov and Maier, 2003
3 1289 ± 35 Ne AB Riaplov and Maier, 2003
5 CS stretch 503 ± 35 Ne AB Riaplov and Maier, 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
2124.5 Ar IR Szczepanski, Hodyss, et al., 1999

Additional references: Jacox, 1994, page 343; Jacox, 2003, page 328; Kasai, Obi, et al., 1993; Gordon, McCarthy, et al., 2001

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Riaplov and Maier, 2003
Riaplov, E.; Maier, J.P., Electronic Absorption Spectra of C, J. Phys. Chem. A, 2003, 107, 42, 8856, https://doi.org/10.1021/jp0351019 . [all data]

Szczepanski, Hodyss, et al., 1999
Szczepanski, J.; Hodyss, R.; Fuller, J.; Vala, M., Infrared Absorption Spectroscopy of Small Carbon-Sulfur Clusters Isolated in Solid Ar, J. Phys. Chem. A, 1999, 103, 16, 2975, https://doi.org/10.1021/jp984700q . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Kasai, Obi, et al., 1993
Kasai, Y.; Obi, K.; Ohshima, Y.; Hirahara, Y.; Endo, Y.; Kawaguchi, K.; Murakami, A., Laboratory detection of C5S by pulsed-discharge-nozzle Fourier transform microwave spectroscopy, Astrophys. J., 1993, 410, L45, https://doi.org/10.1086/186876 . [all data]

Gordon, McCarthy, et al., 2001
Gordon, V.D.; McCarthy, M.C.; Apponi, A.J.; Thaddeus, P., Rotational Spectra of Sulfur-Carbon Chains. I. The Radicals C, Astrophys. J. Suppl., 2001, 134, 2, 311, https://doi.org/10.1086/320853 . [all data]

Notes

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