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palladium

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)8.3369 ± 0.0001eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)696.kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity673.4kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.56213 ± 0.00013N/AScheer, Brodie, et al., 1998B
0.5620 ± 0.0050LPESHo, Ervin, et al., 1991B
0.5580 ± 0.0080LPESFeigerle, Corderman, et al., 1981B

Ionization energy determinations

IE (eV) Method Reference Comment
8.3365 ± 0.0001SIshikawa, 1993LL
8.3369EVALLide, 1992LL
8.3369 ± 0.0001LSCallender, Hackett, et al., 1988LL
8.35 ± 0.05EIRauh and Ackermann, 1979LLK
8.0 ± 0.4EICocke and Gingerich, 1972LLK
8.34SMoore, 1970RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Scheer, Brodie, et al., 1998
Scheer, M.; Brodie, C.A.; Bilodeau, R.C.; Haugen, H.K., Laser spectroscopic measurements of binding energies and fine-structure splittings of Co-, Ni-, Rh-, and Pd-, Phys. Rev. A, 1998, 58, 3, 2051-2062, https://doi.org/10.1103/PhysRevA.58.2051 . [all data]

Ho, Ervin, et al., 1991
Ho, J.; Ervin, K.M.; Polak, M.L.; Gilles, M.K.; Lineberger, W.C., A Study of the Electronic Structures of Pd2- and Pd2 by Photoelectron Spectroscopy, J. Chem. Phys., 1991, 95, 7, 4845, https://doi.org/10.1063/1.461702 . [all data]

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Bobashev, S.V.; Lineberger, W.C., Binding Energies and Structure of Transition Metal Negative Ions, J. Chem. Phys., 1981, 74, 3, 1580, https://doi.org/10.1063/1.441289 . [all data]

Ishikawa, 1993
Ishikawa, T., Photoionization spectra of Pd in high Rydberg states, Jpn. J. Appl. Phys., 1993, 32, 4779. [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Callender, Hackett, et al., 1988
Callender, C.L.; Hackett, P.A.; Rayner, D.M., First-ionization potential of ruthenium, rhodium, and palladium by double-resonance ionization spectroscopy, J. Opt. Soc. Am. B, 1988, 5, 614. [all data]

Rauh and Ackermann, 1979
Rauh, E.G.; Ackermann, R.J., The first ionization potentials of the transition metals, J. Chem. Phys., 1979, 70, 1004. [all data]

Cocke and Gingerich, 1972
Cocke, D.L.; Gingerich, K.A., Mass spectrometric determination of the bond dissociation energies of the molecules CePd and CeC2, J. Phys. Chem., 1972, 76, 2332. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


Notes

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