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Chlorofluoromethyl radical


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   J


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 55250 ± 20 gas Hudgens, Johnson, et al., 1993


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 CH deform. 1280 ± 30 gas MPI Hudgens, Johnson, et al., 1993
4 CCl stretch 910 ± 30 gas MPI Hudgens, Johnson, et al., 1993
5 FCCl scissors 440 ± 30 gas MPI Hudgens, Johnson, et al., 1993
a 6 OPLA 980 ± 30 gas MPI Hudgens, Johnson, et al., 1993

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 49160 ± 20 gas Hudgens, Johnson, et al., 1993


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 CH deform. 1280 ± 30 gas MPI Hudgens, Johnson, et al., 1993
4 CCl stretch 910 ± 30 gas MPI Hudgens, Johnson, et al., 1993
5 FCCl scissors 440 ± 30 gas MPI Hudgens, Johnson, et al., 1993
a 6 OPLA 980 ± 30 gas MPI Hudgens, Johnson, et al., 1993

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

2 H deform. 1283 s Ar IR Prochaska, Keelan, et al., 1979
3 CF stretch 1151 s Ar IR Prochaska, Keelan, et al., 1979
4 CCl stretch 757 m Ar IR Prochaska, Keelan, et al., 1979
6 Umbrella 540 ± 30 gas MPI Hudgens, Johnson, et al., 1993

Additional references: Jacox, 1994, page 176; Prochaska and Andrews, 1980

Notes

mMedium
sStrong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hudgens, Johnson, et al., 1993
Hudgens, J.W.; Johnson, R.D.; Tsai, B.P., New electronic spectra of the CHFCl radical observed with resonance enhanced multiphoton ionization, J. Chem. Phys., 1993, 98, 1925. [all data]

Prochaska, Keelan, et al., 1979
Prochaska, F.T.; Keelan, B.W.; Andrews, L., Infrared spectra of the CHFCl, CHFBr, and CHFI free radicals in solid argon, J. Mol. Spectrosc., 1979, 76, 1-3, 142, https://doi.org/10.1016/0022-2852(79)90223-6 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Prochaska and Andrews, 1980
Prochaska, F.T.; Andrews, L., Infrared and visible absorption spectra and photochemistry of the Ch2FX+, CHFX+, F--H***(CHX)-, and X--H***(CHF)- molecular ions in solid argon, J. Chem. Phys., 1980, 73, 6, 2651, https://doi.org/10.1063/1.440478 . [all data]


Notes

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