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Cyclopentane, chloro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
liquid56.893cal/mol*KN/ADiky, Kabo, et al., 1993 

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
36.424298.15Diky, Kabo, et al., 1993T = 6 to 301 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil387.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil387.35KN/ATimmermans and Hennaut-Roland, 1955Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tfus178.85KN/ATimmermans and Hennaut-Roland, 1955Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Ttriple180.0KN/ADiky, Kabo, et al., 1993, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Deltavap9.271 ± 0.096kcal/molCDiky, Kabo, et al., 1993ALS
Deltavap9.27kcal/molCDiky, Kabo, et al., 1993AC

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
9.2710298.15N/ADiky, Kabo, et al., 1993DH
8.94337.A,EBStephenson and Malanowski, 1987Based on data from 322. - 387. K. See also Andreevskii and Brazhnikov, 1970.; AC

Entropy of vaporization

DeltavapS (cal/mol*K) Temperature (K) Reference Comment
31.09298.15Diky, Kabo, et al., 1993DH

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
0.15180.Diky, Kabo, et al., 1993AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
10.77169.4Diky, Kabo, et al., 1993, 3CAL
0.846180.

Enthalpy of phase transition

DeltaHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.8238169.35crystaline, IIcrystaline, IDiky, Kabo, et al., 1993DH
0.1523180.0crystaline, IliquidDiky, Kabo, et al., 1993DH

Entropy of phase transition

DeltaStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
10.77169.35crystaline, IIcrystaline, IDiky, Kabo, et al., 1993DH
0.846180.0crystaline, IliquidDiky, Kabo, et al., 1993DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H8+10.53HClEILorquet-Julien, 1961 

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 162105

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPetrocol DH762.White, Hackett, et al., 1992100. m/0.25 mm/0.5 «mu»m, He, 1. K/min; Tstart: 30. C; Tend: 220. C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-101760.Zenkevich, 200525. m/0.20 mm/0.10 «mu»m, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryMethyl Silicone804.N/AProgram: not specified
CapillaryMethyl Silicone758.Zenkevich, 1998Program: not specified

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Diky, Kabo, et al., 1993
Diky, V.V.; Kabo, G.J.; Kozyro, A.A.; Krasulin, A.P.; Sevruk, V.M., Thermodynamic properties and pseudorotation of chlorocyclopentane, J. Chem. Thermodyn., 1993, 25, 1169-1181. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Timmermans and Hennaut-Roland, 1955
Timmermans, J.; Hennaut-Roland, M., Work of the International Bureau of Physical-Chemical Standards. IX. The Physical Constants of Twenty Organic Compounds, J. Chim. Phys. Phys.-Chim. Biol., 1955, 52, 223. [all data]

Diky, Kabo, et al., 1993, 2
Diky, V.V.; Kabo, G.Ya.; Kozyro, A.A.; Krasulin, A.P.; Sevruk, V.M., Thermodynamic Properties and Pseudorotation of Chlorocyclopentane, J. Chem. Thermodyn., 1993, 25, 1169-81. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Andreevskii and Brazhnikov, 1970
Andreevskii, D.N.; Brazhnikov, M.M., Vestn. Beloruss. Univ., 1970, 2, 3, 14. [all data]

Diky, Kabo, et al., 1993, 3
Diky, V.V.; Kabo, G.J.; Kozyro, A.A.; Krasulin, A.P.; Sevruk, V.M., Thermodynamic properties and pseudorotation of chlorocyclopentane, J. Chem. Thermodyn., 1993, 25, 10, 1169, https://doi.org/10.1006/jcht.1993.1114 . [all data]

Lorquet-Julien, 1961
Lorquet-Julien, J.C., Comportement du 1 fluoro- et du 1 chloropentane normal et des derives halogenescorrespondants du cyclopentane sous l'impact electronique, Bull. Soc. Roy. Sci. Liege, 1961, 30, 170. [all data]

White, Hackett, et al., 1992
White, C.M.; Hackett, J.; Anderson, R.R.; Kail, S.; Spock, P.S., Linear temperature programmed retention indices of gasoline range hydrocarbons and chlorinated hydrocarbons on cross-linked polydimethylsiloxane, J. Hi. Res. Chromatogr., 1992, 15, 2, 105-120, https://doi.org/10.1002/jhrc.1240150211 . [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]

Zenkevich, 1998
Zenkevich, I.G., Reciprocally Unambiguous Conformity Between GC Retention Indices and Boiling Points within Two- and Multidimensional Taxonomic Groups of Organic Compounds, J. Hi. Res. Chromatogr., 1998, 21, 10, 565-568, https://doi.org/10.1002/(SICI)1521-4168(19981001)21:10<565::AID-JHRC565>3.0.CO;2-6 . [all data]


Notes

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