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Trifluorovinyl radical


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 C=C stretch 1780.4 w m Ar IR Wurfel, Thoma, et al., 1992
2 CF stretch 1290 ± 5 gas IR DL Wurfel, Pugliano, et al., 1991
2 CF stretch 1282.4 s Ar IR Wurfel, Thoma, et al., 1992
3 CF stretch 1225 ± 5 gas IR DL Wurfel, Pugliano, et al., 1991
3 CF stretch 1216.9 vs Ar IR Wurfel, Thoma, et al., 1992
4 C2F3 s-stretch 900.0 w Ar IR Wurfel, Thoma, et al., 1992

Additional references: Jacox, 1994, page 287

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wurfel, Thoma, et al., 1992
Wurfel, B.E.; Thoma, A.; Bondybey, V.E., Vibrational spectroscopy of C2F3 in an Ar matrix, Chem. Phys. Lett., 1992, 198, 1-2, 135, https://doi.org/10.1016/0009-2614(92)90061-Q . [all data]

Wurfel, Pugliano, et al., 1991
Wurfel, B.E.; Pugliano, N.; Bradforth, S.E.; Saykally, R.J.; Pimentel, G.C., Broadband transient infrared laser spectroscopy of trifluorovinyl radical C2F3.cntdot.: experimental and ab initio results, J. Phys. Chem., 1991, 95, 7, 2932, https://doi.org/10.1021/j100160a052 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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