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2-Norbornene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil369.2KN/AWeast and Grasselli, 1989BS
Tboil368.87KN/AAnonymous, 1942Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tfus319.KN/ALebedev, Smirnova, et al., 1992Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC
Tfus317. - 317.6KN/ABuckingham and Donaghy, 1982BS
Tfus318.9KN/AAnonymous, 1942Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Ttriple319.5KN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tc590.KN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc48.60barN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 2.50 bar; from extraploation of obs. vapor pressures to Tc; TRC
Quantity Value Units Method Reference Comment
rhoc3.181mol/lN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 0.15 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap35.1 ± 0.2kJ/molEBSteele, Chirico, et al., 1996Based on data from 338. - 406. K.; AC
Deltavap33.6 ± 0.08kJ/molVHall, Smith, et al., 1973ALS
Deltavap33.6kJ/molN/AHall, Smith, et al., 1973DRB
Quantity Value Units Method Reference Comment
Deltasub38. ± 1.kJ/molAVGN/AAverage of 10 values; Individual data points

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
367. - 370.0.987Buckingham and Donaghy, 1982BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
33.0 ± 0.2340.EBSteele, Chirico, et al., 1996Based on data from 338. - 406. K.; AC
30.8 ± 0.3380.EBSteele, Chirico, et al., 1996Based on data from 338. - 406. K.; AC
34.3316.AStephenson and Malanowski, 1987Based on data from 301. - 350. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
3.48319.5Lebedev, Smirnova, et al., 1992, 2See also Smirnova, Lebedev, et al., 1992.; AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
32.77130.3Lebedev, Vasil'yev, et al., 1993CAL
10.89319.5

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Anonymous, 1942
Anonymous, R., , Am. Pet. Inst. Res. Proj. 6, Natl. Bur. Stand., 1942. [all data]

Lebedev, Smirnova, et al., 1992
Lebedev, B.; Smirnova, N.; Kiparisova, Y.; Makovetsky, K., Makromol. Chem., 1992, 193, 6, 1399, https://doi.org/10.1002/macp.1992.021930616 . [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Steele, Chirico, et al., 1996
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Smith, N.K., Thermodynamic properties and ideal-gas enthalpies of formation for butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol, J. Chem. Eng. Data, 1996, 41, 1285-1302. [all data]

Hall, Smith, et al., 1973
Hall, H.K., Jr.; Smith, C.D.; Baldt, J.H., Enthalpies of formation of norticyclene, norbornene, norbornadiene, and quadricyclane, J. Am. Chem. Soc., 1973, 95, 3197-3201. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Lebedev, Smirnova, et al., 1992, 2
Lebedev, Boris; Smirnova, Natal'ya; Kiparisova, Yelena; Makovetsky, Kirill, Makromol. Chem., 1992, 193, 6, 1399-1411, https://doi.org/10.1002/macp.1992.021930616 . [all data]

Smirnova, Lebedev, et al., 1992
Smirnova, N.N.; Lebedev, B.V.; Kiparisova, E.G.; Makovetskii, K.L.; Gorbacheva, L.I., Thermodynamics of norbornene, its polymerization, and the formed polynorbornene in the 0-330 K region, Vysokomol. Soed. A, 1992, 34, 1, 77. [all data]

Lebedev, Vasil'yev, et al., 1993
Lebedev, B.; Vasil'yev, V.; Novosyolova, N., Makromol. Chem., 1993, 194, 2, 739, https://doi.org/10.1002/macp.1993.021940231 . [all data]


Notes

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