Acetic acid, methyl ester

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-445.89kJ/molCcrHall and Baldt, 1971ALS
Quantity Value Units Method Reference Comment
Δcliquid-1583.kJ/molCcbSeno, Tsuchiya, et al., 1975Corresponding Δfliquid = -455.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-1592.2 ± 0.67kJ/molCcrHall and Baldt, 1971Corresponding Δfliquid = -445.85 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
140.2288.58Okamoto, Oguni, et al., 1992T = 13 to 290 K. Unsmoothed experimental datum.; DH
141.34298.15Pintos, Bravo, et al., 1988DH
140.6298.15Costas and Patterson, 1985T = 283.15, 298.15, 313.15 K.; DH
140.56298.15Costas and Patterson, 1985, 2T = 283.15, 298.15, 313.15 K.; DH
123.7297.Hall and Baldt, 1971DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hall and Baldt, 1971
Hall, H.K., Jr.; Baldt, J.H., Thermochemistry of strained-ring bridgehead nitriles and esters, J. Am. Chem. Soc., 1971, 93, 140-145. [all data]

Seno, Tsuchiya, et al., 1975
Seno, M.; Tsuchiya, S.; Kise, H.; Asahara, T., Studies on bond character in phosphorus ylides by combustion heat and x-ray photoelectron spectroscopy, Bull. Chem. Soc. Jpn., 1975, 48, 2001-2005. [all data]

Okamoto, Oguni, et al., 1992
Okamoto, N.; Oguni, M.; Suga, H., Low temperature calorimetric study of methyl acetate, Thermochim. Acta, 1992, 202, 215-222. [all data]

Pintos, Bravo, et al., 1988
Pintos, M.; Bravo, R.; Baluja, M.C.; Paz Andrade, M.I.; Roux-Desgranges, G.; Grolier, J.-P.E., Can. J. Chem., 1988, 1179. [all data]

Costas and Patterson, 1985
Costas, M.; Patterson, D., Heat capacities of water + organic-solvent mixtures, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 2381-2398. [all data]

Costas and Patterson, 1985, 2
Costas, M.; Patterson, D., Self-association of alcohols in inert solvents, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 635-654. [all data]


Notes

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