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Iron dioxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.358 ± 0.030LPESWang, Wu, et al., 1996B
2.360 ± 0.030LPESWu, Desai, et al., 1996B
2.358 ± 0.030LPESFan and Wang, 1995B
2.76 ± 0.25R-AKaibicheva, Rudnyi, et al., 1992value altered from reference due to conversion from electron convention to ion convention; B

Ionization energy determinations

IE (eV) Method Reference Comment
9.5 ± 0.5EIHildenbrand, 1975LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Wu, et al., 1996
Wang, L.S.; Wu, H.; Desai, S.R., Sequential Oxygen Atom Chemisorption on Surfaces of Small Iron Clusters, Phys. Rev. Lett., 1996, 76, 25, 4853, https://doi.org/10.1103/PhysRevLett.76.4853 . [all data]

Wu, Desai, et al., 1996
Wu, H.; Desai, R.; Wang, L.-S., Observation and Photoelectron Spectroscopic Study of Novel Mono- and Di-iron Oxide Molecules: FeOy- (y=1-4) and Fe2Oy- (y=1-5), J. Am. Chem. Soc., 1996, 118, 22, 5296, https://doi.org/10.1021/ja954153b . [all data]

Fan and Wang, 1995
Fan, J.W.; Wang, L.S., Photoelectron spectroscopy of FeO- and FeO2-: Observation of low-spin excited states of FeO and determination of the electron affinity of Fe, J. Chem. Phys., 1995, 102, 22, 8714, https://doi.org/10.1063/1.468974 . [all data]

Kaibicheva, Rudnyi, et al., 1992
Kaibicheva, E.A.; Rudnyi, E.B.; Sidorov, L.N., Determination of Affinity to FeO2 Electron by the Ion-Molecular Equilibrium Method, Zh. Fiz. Khim. SSSR, 1992, 66, 3153. [all data]

Hildenbrand, 1975
Hildenbrand, D.L., Thermochemistry of molecular FeO, FeO+ and FeO2, Chem. Phys. Lett., 1975, 34, 352. [all data]


Notes

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