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NO2+


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

NO2+ + Nitrous oxide = (NO2+ bullet Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ bullet N2O)

Quantity Value Units Method Reference Comment
Deltar59.0kJ/molEICameron, Aitken, et al., 1994gas phase
Deltar72.8kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar55. ± 3.kJ/molDTIllies, 1988gas phase; «DELTA»rH(0 K)=55.7 kJ/mol
Deltar54.8kJ/molPILinn and Ng, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar51.9J/mol*KDTIllies, 1988gas phase; «DELTA»rH(0 K)=55.7 kJ/mol

(NO2+ bullet 5Nitrous oxide) + Nitrous oxide = (NO2+ bullet 6Nitrous oxide)

By formula: (NO2+ bullet 5N2O) + N2O = (NO2+ bullet 6N2O)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(NO2+ bullet 2Nitrous oxide) + Nitrous oxide = (NO2+ bullet 3Nitrous oxide)

By formula: (NO2+ bullet 2N2O) + N2O = (NO2+ bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar12.kJ/molEICameron, Aitken, et al., 1994gas phase
Deltar23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ bullet Nitrous oxide) + Nitrous oxide = (NO2+ bullet 2Nitrous oxide)

By formula: (NO2+ bullet N2O) + N2O = (NO2+ bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molEICameron, Aitken, et al., 1994gas phase
Deltar24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ bullet 10Nitrogen) + Nitrogen = (NO2+ bullet 11Nitrogen)

By formula: (NO2+ bullet 10N2) + N2 = (NO2+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar77.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 11Nitrogen) + Nitrogen = (NO2+ bullet 12Nitrogen)

By formula: (NO2+ bullet 11N2) + N2 = (NO2+ bullet 12N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 9Nitrogen) + Nitrogen = (NO2+ bullet 10Nitrogen)

By formula: (NO2+ bullet 9N2) + N2 = (NO2+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar86.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 2Nitrogen) + Nitrogen = (NO2+ bullet 3Nitrogen)

By formula: (NO2+ bullet 2N2) + N2 = (NO2+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar18. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 3Nitrogen) + Nitrogen = (NO2+ bullet 4Nitrogen)

By formula: (NO2+ bullet 3N2) + N2 = (NO2+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 4Nitrogen) + Nitrogen = (NO2+ bullet 5Nitrogen)

By formula: (NO2+ bullet 4N2) + N2 = (NO2+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 5Nitrogen) + Nitrogen = (NO2+ bullet 6Nitrogen)

By formula: (NO2+ bullet 5N2) + N2 = (NO2+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 6Nitrogen) + Nitrogen = (NO2+ bullet 7Nitrogen)

By formula: (NO2+ bullet 6N2) + N2 = (NO2+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 7Nitrogen) + Nitrogen = (NO2+ bullet 8Nitrogen)

By formula: (NO2+ bullet 7N2) + N2 = (NO2+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 8Nitrogen) + Nitrogen = (NO2+ bullet 9Nitrogen)

By formula: (NO2+ bullet 8N2) + N2 = (NO2+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet Nitrogen) + Nitrogen = (NO2+ bullet 2Nitrogen)

By formula: (NO2+ bullet N2) + N2 = (NO2+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ bullet 3Nitrous oxide) + Nitrous oxide = (NO2+ bullet 4Nitrous oxide)

By formula: (NO2+ bullet 3N2O) + N2O = (NO2+ bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ bullet 4Nitrous oxide) + Nitrous oxide = (NO2+ bullet 5Nitrous oxide)

By formula: (NO2+ bullet 4N2O) + N2O = (NO2+ bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

NO2+ + Nitrogen = (NO2+ bullet Nitrogen)

By formula: NO2+ + N2 = (NO2+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

NO2+ + Water = (NO2+ bullet Water)

By formula: NO2+ + H2O = (NO2+ bullet H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
67.4 (+9.6,-0.) PD/KERDGraul, Kim, et al., 1992gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W., Appearence Energies of Small Cluster Ions and their Fragments, J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935 . [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Linn and Ng, 1981
Linn, S.H.; Ng, C.Y., Photoionization Study of CO2, N2O Dimers and Clusters, J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931 . [all data]

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., How are Nitrogen Molecules Bound to NO2+ and NO+?, J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880 . [all data]

Graul, Kim, et al., 1992
Graul, S.T.; Kim, H.S.; Bowers, M.T., The Dynamics of Photodissociation of the Gas Phase (N2O.H2O)+ Cluster Ion, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 507, https://doi.org/10.1016/0168-1176(92)80111-D . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References