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Indenyl radical


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C9H7+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.852 ± 0.013LPDRömer, Janaway, et al., 1997 Bordwell and Satish, 1992 has DH = 78.7 kcal/mol (sDEA); B

Ionization energy determinations

IE (eV) Method Reference Comment
8.35EIPottie and Lossing, 1963RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Römer, Janaway, et al., 1997
Römer, B.; Janaway, G.; Brauman, J.I., Cyclopentadienyl, Indenyl, and Fluorenyl Anions: Gas-Phase and Solvation Energy Contributions to Electron Detachment Energies, J. Am. Chem. Soc., 1997, 119, 9, 2249, https://doi.org/10.1021/ja961947x . [all data]

Bordwell and Satish, 1992
Bordwell, F.G.; Satish, A.V., Acidities of Indenes and Their Radical Cations - Homolytic Bond Dissociation Energies of the Benzylic C-H Bonds in Indenes, J. Chem. Soc. Chem. Comm., 1992, 114, 26, 10173, https://doi.org/10.1021/ja00052a013 . [all data]

Pottie and Lossing, 1963
Pottie, R.F.; Lossing, F.P., Free radicals by mass spectrometry. XXIX. Ionization potentials of substituted cyclopentadienyl radicals, J. Am. Chem. Soc., 1963, 85, 269. [all data]


Notes

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