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Trimethylindium


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltasub48.5 ± 2.5kJ/molN/APilcher and Skinner, 1983See also Clark and Price, 1968.; AC
Deltasub48.5 ± 2.5kJ/molRSCDennis, Work, et al., 1934MS

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
62.7294.N/AFulem, Ruzicka, et al., 2004Based on data from 274. - 313. K.; AC
57.7344.AStephenson and Malanowski, 1987Based on data from 328. - 362. K. See also Laubengayer and Gilliam, 1941.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
14.300358.7Ur'yash, Ronina, et al., 1991DH
14.3358.7Ur'yash, Ronina, et al., 1991, 2AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Clark and Price, 1968
Clark, W.D.; Price, S.J.W., Determination of the heat of formation of trimethylindium and calculation of the mean In---CH 3 bond dissociation energy, Can. J. Chem., 1968, 46, 10, 1633-1634, https://doi.org/10.1139/v68-272 . [all data]

Dennis, Work, et al., 1934
Dennis, L.M.; Work, R.W.; Rochow, E.G.; Chamot, E.M., J. Am. Chem. Soc., 1934, 56, 1047. [all data]

Fulem, Ruzicka, et al., 2004
Fulem, M.; Ruzicka, K.; Ruzicka, V.; Hulicius, E.; Simecek, T.; Pangrác, J.; Rushworth, S.A.; Smith, L.M., Measurement of vapour pressure of In-based metalorganics for MOVPE, Journal of Crystal Growth, 2004, 272, 1-4, 42-46, https://doi.org/10.1016/j.jcrysgro.2004.09.001 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Laubengayer and Gilliam, 1941
Laubengayer, A.W.; Gilliam, W.F., The Alkyls of the Third Group Elements. I. Vapor Phase Studies of the Alkyls of Aluminum, Gallium and Indium 1, J. Am. Chem. Soc., 1941, 63, 2, 477-479, https://doi.org/10.1021/ja01847a031 . [all data]

Ur'yash, Ronina, et al., 1991
Ur'yash, V.F.; Ronina, O.V.; Karataev, E.N.; Zimina, I.D., Physicochemical study of alkyl derivatives of indium, Metalloorg. Khim., 1991, 4(5), 1050-1054. [all data]

Ur'yash, Ronina, et al., 1991, 2
Ur'yash, V.F.; Ronina, O.V.; Karataev, E.N.; Zimina, I.V.; Kuznetsova, T.V.; Petrun, T.V.; Feshchenko, I.A.; Zorin, A.D., Physicochemical study of alkyl derivatives of indium, Metalloogranicheskaya Khimiya, 1991, 4, 5, 1050. [all data]


Notes

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