Naphthalene, 2-chloro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid55.2 ± 8.4kJ/molCcbSmith, Bjellerup, et al., 1953Heat of formation derived by Cox and Pilcher, 1970; ALS
Quantity Value Units Method Reference Comment
Δcsolid-5014.5 ± 8.4kJ/molCcbSmith, Bjellerup, et al., 1953Reanalyzed by Cox and Pilcher, 1970, Original value = -5007.16 kJ/mol; ALS
Quantity Value Units Method Reference Comment
solid,1 bar202.13J/mol*KN/AVan Miltenburg and Verdonk, 1991DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
235.64298.15Van Miltenburg and Verdonk, 1991T = 5 to 370 K. There is an extended solid-to-solid transition between 260 and 309 K, of two regions, between 260-290 and 290-309 K.; DH
150.250.Loyzance, Rey-Lafon, et al., 1978T = 4.2 to 300 K. Data given graphically and estimated from graph. Transition at 308 K makes heat capacity at 298 K anomalous.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Smith, Bjellerup, et al., 1953
Smith, L.; Bjellerup, L.; Krook, S.; Westermark, H., Heats of combustion of organic chloro compounds determined by the "quartz wool" method, Acta Chem. Scand., 1953, 7, 65. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Van Miltenburg and Verdonk, 1991
Van Miltenburg, J.C.; Verdonk, M.L., Molar heat capacities of 2-chloronaphthalene at temperatures between 5K and 370K, J. Chem. Thermodynam., 1991, 23, 273-279. [all data]

Loyzance, Rey-Lafon, et al., 1978
Loyzance, P.L.; Rey-Lafon, M.; Bonjour, E., Vibrational and calorimetric study of polymorphism in 2-fluoro and 2-chloronaphthalene - nature of disorder, J. Phys. Chem. Solids, 1978, 39, 967-970. [all data]


Notes

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