Dibenzothiophene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid24.9 ± 1.1kcal/molCcrSabbah and Antipine, 1987see Sabbah, 1979; ALS
Δfsolid28.76 ± 0.35kcal/molCcrGood, 1972ALS
Quantity Value Units Method Reference Comment
Δcsolid-1570.7 ± 1.1kcal/molCcrSabbah and Antipine, 1987see Sabbah, 1979; ALS
Δcsolid-1574.49 ± 0.32kcal/molCcrGood, 1972ALS
Quantity Value Units Method Reference Comment
solid,1 bar48.805cal/mol*KN/AChirico, Knipmeyer, et al., 1991DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
47.395298.15Chirico, Knipmeyer, et al., 1991T = 5 to 800 K.; DH
46.51298.15O'Rourke and Mraw, 1983T = 220 to 560 K. Cp = 0.6709 (T/K) - 5.4 (220 to 371.0 K) J/mol*K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sabbah and Antipine, 1987
Sabbah, R.; Antipine, I., Thermodynamic study on four polycycles. Relationship between their energy values and their structure, Bull. Soc. Chim. Fr., 1987, 392-400. [all data]

Sabbah, 1979
Sabbah, R., Thermodynamique de substances soufrees. I. Etude thermochimique du benzo-2,3 thiophene et du dibenzothiophene, Bull. Soc. Chim. France, 1979, 9, 434-437. [all data]

Good, 1972
Good, W.D., Enthalpies of combustion of 18 organic sulfur compounds related to petroleum, J. Chem. Eng. Data, 1972, 17, 158-162. [all data]

Chirico, Knipmeyer, et al., 1991
Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Steele, W.V., The thermodynamic properties of dibenzothiophene, J. Chem. Thermodyn., 1991, 23, 431-450. [all data]

O'Rourke and Mraw, 1983
O'Rourke, D.F.; Mraw, S.C., Heat capacities and enthalpies of fusion of dibenzothiophene (220 to 560 K) and of biphenyl, cyclohexylbenzene, and cyclohexylcyclohexane (220 to 475 K). Enthalpies and temperatures of three transitions in solid cyclohexylcyclohexane, J. Chem. Thermodynam., 1983, 15, 489-502. [all data]


Notes

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