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HSSH


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a 1 SH s-stretch 2555.78 gas IR Winnewisser and Winnewisser, 1968
Winnewisser, 1970
1 SH s-stretch 2553.8 Ar IR Isoniemi, Khriachtchev, et al., 1999
2 Deformation 883 gas IR Winnewisser and Winnewisser, 1968
2 Deformation 880.3 Ar IR Isoniemi, Khriachtchev, et al., 1999
3 SS stretch 515.92 gas IR MW Winnewisser and Winnewisser, 1968
Urban, Behrend, et al., 1993
4 Torsion 417.48 gas IR Redington, 1962
Winnewisser and Winnewisser, 1968
Urban, Herbst, et al., 1989
Urban, Behrend, et al., 1993
b 5 SH a-stretch 2558.63 gas IR Wilson and Badger, 1949
Winnewisser and Winnewisser, 1968
Winnewisser, 1970
Mittler, Yamada, et al., 1994
5 SH a-stretch 2556.6 Ar IR Isoniemi, Khriachtchev, et al., 1999
6 Deformation 882.0 gas IR Wilson and Badger, 1949
Winnewisser and Winnewisser, 1968

Additional references: Jacox, 1994, page 155; Jacox, 1998, page 230; Jacox, 2003, page 178; Winnewisser, Winnewisser, et al., 1968; Winnewisser, 1972; Winnewisser and Helminger, 1972; Winnewisser and Helminger, 1972, 2; Winnewisser, 1972, 2; Plummer, Winnewisser, et al., 1987; Behrend, Mittler, et al., 1990; Behrend, Mittler, et al., 1991; Pelz, Yamada, et al., 1993; Yamada, Behrend, et al., 1996


References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Winnewisser and Winnewisser, 1968
Winnewisser, B.P.; Winnewisser, M., Z. Naturforsch., 1968, 23a, 832. [all data]

Winnewisser, 1970
Winnewisser, B.P., High resolution infrared spectrum of «nu»1 and «nu»5 of disulfane, J. Mol. Spectrosc., 1970, 36, 3, 414, https://doi.org/10.1016/0022-2852(70)90218-3 . [all data]

Isoniemi, Khriachtchev, et al., 1999
Isoniemi, E.; Khriachtchev, L.; Pettersson, M.; Rasanen, M., Infrared spectroscopy and 266 nm photolysis of H2S2 in solid Ar, Chem. Phys. Lett., 1999, 311, 1-2, 47, https://doi.org/10.1016/S0009-2614(99)00756-3 . [all data]

Urban, Behrend, et al., 1993
Urban, S.; Behrend, J.; Yamada, K.M.T.; Winnewisser, G., Coriolis Interactions between the Fundamental Stretching and Torsional-Vibrational States of Disulfane (H2S2), J. Mol. Spectrosc., 1993, 161, 2, 511, https://doi.org/10.1006/jmsp.1993.1255 . [all data]

Redington, 1962
Redington, R.L., The infrared spectrum and barriers hindering internal rotation in H2S2, CF3SH, and CF3SD, J. Mol. Spectrosc., 1962, 9, 469, https://doi.org/10.1016/0022-2852(62)90252-7 . [all data]

Urban, Herbst, et al., 1989
Urban, S.; Herbst, E.; Mittler, P.; Winnewisser, G.; Yamada, K.M.T.; Winnewisser, M., The high-resolution rotational and torsional spectra of HSSH, J. Mol. Spectrosc., 1989, 137, 2, 327, https://doi.org/10.1016/0022-2852(89)90177-X . [all data]

Wilson and Badger, 1949
Wilson, M.K.; Badger, R.M., The Infra-Red Spectrum and Molecular Configuration of Hydrogen Persulfide, J. Chem. Phys., 1949, 17, 12, 1232, https://doi.org/10.1063/1.1747148 . [all data]

Mittler, Yamada, et al., 1994
Mittler, P.; Yamada, K.M.T.; Winnewisser, G.; Birk, M., High-Resolution FTIR Spectrum of HSSH in the SH-Stretching Region: The «nu»5 Band, J. Mol. Spectrosc., 1994, 164, 2, 390, https://doi.org/10.1006/jmsp.1994.1083 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Winnewisser, Winnewisser, et al., 1968
Winnewisser, G.; Winnewisser, M.; Gordy, W., Millimeter-Wave Rotational Spectrum of HSSH and DSSD. I. Q Branches, J. Chem. Phys., 1968, 49, 8, 3465, https://doi.org/10.1063/1.1670621 . [all data]

Winnewisser, 1972
Winnewisser, G., Millimeter Wave Rotational Spectrum of HSSH and DSSD. II. Anomalous K Doubling Caused by Centrifugal Distortion in DSSD, J. Chem. Phys., 1972, 56, 6, 2944, https://doi.org/10.1063/1.1677629 . [all data]

Winnewisser and Helminger, 1972
Winnewisser, G.; Helminger, P., Millimeter Wave Rotational Spectrum of HSSH and DSSD. III. Q Branches of DSSD, J. Chem. Phys., 1972, 56, 6, 2954, https://doi.org/10.1063/1.1677630 . [all data]

Winnewisser and Helminger, 1972, 2
Winnewisser, G.; Helminger, P., Millimeter Wave Rotational Spectrum of HSSH and DSSD. IV. P, Q, and R Branches of HSSH, J. Chem. Phys., 1972, 56, 6, 2967, https://doi.org/10.1063/1.1677631 . [all data]

Winnewisser, 1972, 2
Winnewisser, G., Direct Observation of the Anomalous K Doubling Caused by Centrifugal Distortion in HSSH, J. Chem. Phys., 1972, 57, 4, 1803, https://doi.org/10.1063/1.1678483 . [all data]

Plummer, Winnewisser, et al., 1987
Plummer, G.M.; Winnewisser, G.; Winnewisser, M.; Hahn, J.; Reinartz, K., HSSH revisited: The high-resolution Fourier transform spectrum of the ground state between 30 and 90 cm-1, J. Mol. Spectrosc., 1987, 126, 2, 255, https://doi.org/10.1016/0022-2852(87)90235-9 . [all data]

Behrend, Mittler, et al., 1990
Behrend, J.; Mittler, P.; Winnewisser, G.; Yamada, K.M.T.; Winnewisser, M., Complete rotational analysis of the ground state of HSSH, J. Mol. Spectrosc., 1990, 141, 2, 265, https://doi.org/10.1016/0022-2852(90)90163-K . [all data]

Behrend, Mittler, et al., 1991
Behrend, J.; Mittler, P.; Winnewisser, G.; Yamada, K.M.T., Spectra of deuterated disulfane and spectroscopic determination of its molecular structure, J. Mol. Spectrosc., 1991, 150, 1, 99, https://doi.org/10.1016/0022-2852(91)90196-H . [all data]

Pelz, Yamada, et al., 1993
Pelz, G.; Yamada, K.M.T.; Winnewisser, G., Torsional Dependence of the Effective Rotational Constants of H2O2 and H2S2, J. Mol. Spectrosc., 1993, 159, 2, 507, https://doi.org/10.1006/jmsp.1993.1146 . [all data]

Yamada, Behrend, et al., 1996
Yamada, K.M.T.; Behrend, J.; Belov, S.P.; Winnewisser, G., AnomalousK-Type Doubling of HSSH, J. Mol. Spectrosc., 1996, 176, 2, 397, https://doi.org/10.1006/jmsp.1996.0101 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References