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Di-tert-butyl peroxide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil382.7KN/AAldrich Chemical Company Inc., 1990BS
Quantity Value Units Method Reference Comment
Deltavap9.5 ± 0.7kcal/molAVGN/AAverage of 9 values; Individual data points

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
8.84333.N/ADiogo H.P., 1995Based on data from 308. - 358. K.; AC
7.65261.AStephenson and Malanowski, 1987Based on data from 246. - 311. K. See also Indritz, Stone, et al., 1978.; AC
7.41288.AStephenson and Malanowski, 1987Based on data from 273. - 384. K. See also Egerton, Emte, et al., 1951.; AC
7.420253.VEgerton, Emte, et al., 1951ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Diogo H.P., 1995
Diogo H.P., Standard enthalpy of formation and enthalpy of vaporization of di-1,1-dimethyl peroxide. Reevaluation of the standard enthalpy of formation of the di-1,1-dimethylethoxy radical, J. Chem. Thermodyn., 1995, 27, 597-604. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Indritz, Stone, et al., 1978
Indritz, Doren; Stone, Jack; Williams, Frederick, Vapor pressure of di-tert-butyl peroxide, J. Chem. Eng. Data, 1978, 23, 1, 6-7, https://doi.org/10.1021/je60076a002 . [all data]

Egerton, Emte, et al., 1951
Egerton, A.C.; Emte, W.; Minkoff, G.J., Some properties of organic peroxides, Faraday Discuss. Chem. Soc., 1951, 10, 278. [all data]


Notes

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