CH3O2

• Formula: CH₃O₂
• Molecular weight: 47.0333
• CAS Registry Number: 2143-58-0
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?

State:   A

State:   X

Additional references: Jacox, 1994, page 321; Jacox, 2003, page 320; Hartmann, Karthauser, et al., 1990; Wu, Dupre, et al., 2007

Notes

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Parkes, Paul, et al., 1973
Parkes, D.A.; Paul, D.M.; Quinn, C.P.; Robson, R.C., The ultraviolet absorption by alkylperoxy radicals and their mutual reactions, Chem. Phys. Lett., 1973, 23, 3, 425, https://doi.org/10.1016/0009-2614(73)85115-2 . [all data]

Hochanadel, Ghormley, et al., 1977
Hochanadel, C.J.; Ghormley, J.A.; Boyle, J.W.; Ogren, P.J., Absorption spectrum and rates of formation and decay of the methyldioxy radical, J. Phys. Chem., 1977, 81, 1, 3, https://doi.org/10.1021/j100516a002 . [all data]

Anastasi, Smith, et al., 1978
Anastasi, C.; Smith, I.W.M.; Parkes, D.A., J. Chem. Soc., 1978, Faraday Trans. 1 74, 1693. [all data]

McAdam, Veyret, et al., 1987
McAdam, K.; Veyret, B.; Lesclaux, R., UV absorption spectra of HO2 and CH3O2 radicals and the kinetics of their mutual reactions at 298 K, Chem. Phys. Lett., 1987, 133, 1, 39, https://doi.org/10.1016/0009-2614(87)80049-0 . [all data]

Dagaut and Kurylo, 1990
Dagaut, P.; Kurylo, M.J., The gas phase UV absorption spectrum of CH3O2 radicals: A reinvestigation, J. Photochem. Photobiol. A: Chem., 1990, 51, 2, 133, https://doi.org/10.1016/1010-6030(90)87047-F . [all data]

Maricq and Wallington, 1992
Maricq, M.M.; Wallington, T.J., Absolute UV cross sections of methyl and ethyl peroxy radicals, J. Phys. Chem., 1992, 96, 2, 986, https://doi.org/10.1021/j100181a081 . [all data]

Hunziker and Wendt, 1976
Hunziker, H.E.; Wendt, H.R., Electronic absorption spectra of organic peroxyl radicals in the near infrared, J. Chem. Phys., 1976, 64, 8, 3488, https://doi.org/10.1063/1.432606 . [all data]

Pushkarsky, Zalyubovsky, et al., 2000
Pushkarsky, M.B.; Zalyubovsky, S.J.; Miller, T.A., Detection and characterization of alkyl peroxy radicals using cavity ringdown spectroscopy, J. Chem. Phys., 2000, 112, 24, 10695, https://doi.org/10.1063/1.481705 . [all data]

Blanksby, Ramond, et al., 2001
Blanksby, S.J.; Ramond, T.M.; Davico, G.E.; Nimlos, M.R.; Kato, S.; Bierbaum, V.M.; Lineberger, W.C.; Ellison, G.B.; Okumura, M., Negative-Ion Photoelectron Spectroscopy, Gas-Phase Acidity, and Thermochemistry of the Peroxyl Radicals CH, J. Am. Chem. Soc., 2001, 123, 39, 9585, https://doi.org/10.1021/ja010942j . [all data]

Fu, Hu, et al., 2006
Fu, H.B.; Hu, Y.J.; Bernstein, E.R., Generation and detection of alkyl peroxy radicals in a supersonic jet expansion, J. Chem. Phys., 2006, 125, 1, 014310, https://doi.org/10.1063/1.2209680 . [all data]

Chung, Chang, et al., 2007
Chung, C.-Y.; Chang, C.-W.; Lee, Y.-P.; Liao, H.-Y.; Sharp, E.N.; Rupper, P.; Miller, T.A., Rovibronic bands of the A←X transition of CH[sub 3]OO and CD[sub 3]OO detected with cavity ringdown absorption near 1.2--1.4 μm, J. Chem. Phys., 2007, 127, 4, 044311, https://doi.org/10.1063/1.2747616 . [all data]

Huang, Chu, et al., 2007
Huang, D.-R.; Chu, L.-K.; Lee, Y.-P., Infrared absorption of gaseous CH[sub 3]OO detected with a step-scan Fourier-transform spectrometer, J. Chem. Phys., 2007, 127, 23, 234318, https://doi.org/10.1063/1.2807241 . [all data]

Morrison, Agarwal, et al., 2012
Morrison, A.M.; Agarwal, J.; Schaefer, H.F., III; Douberly, G.E., Infrared Laser Spectroscopy of the CH, J. Phys. Chem. A, 2012, 116, 22, 5299, https://doi.org/10.1021/jp3026368 . [all data]

Nandi, Blanksby, et al., 2002
Nandi, S.; Blanksby, S.J.; Zhang, X.; Nimlos, M.R.; Dayton, D.C.; Ellison, G.B., Polarized Infrared Absorption Spectrum of Matrix-Isolated Methylperoxyl Radicals, CH, J. Phys. Chem. A, 2002, 106, 33, 7547, https://doi.org/10.1021/jp0126816 . [all data]

Ase, Bock, et al., 1986
Ase, P.; Bock, W.; Snelson, A., Alkylperoxy and alkyl radicals. 1. Infrared spectra of CH3O2 and CH3O4CH3 and the ultraviolet photolysis of CH3O2 in argon + oxygen matrixes, J. Phys. Chem., 1986, 90, 10, 2099, https://doi.org/10.1021/j100401a024 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Hartmann, Karthauser, et al., 1990
Hartmann, D.; Karthauser, J.; Zellner, R., The 248-nm photofragmentation of the peroxymethyl radical, J. Phys. Chem., 1990, 94, 7, 2963, https://doi.org/10.1021/j100370a042 . [all data]

Wu, Dupre, et al., 2007
Wu, S.; Dupre, P.; Rupper, P.; MIlller, T.A., The vibrationless A←X transition of the jet-cooled deuterated methyl peroxy radical CD[sub 3]O[sub 2] by cavity ringdown spectroscopy, J. Chem. Phys., 2007, 127, 22, 224305, https://doi.org/10.1063/1.2802202 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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