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PH3F2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a2 3 PH3 deform. 1266.15 m gas IR Seel and Velleman, 1971
Beckers, Breidung, et al., 1990
Beckers, 1993
4 PF2 a-stretch 755.99 vs gas IR Seel and Velleman, 1971
Beckers, Breidung, et al., 1990
Beckers, 1993
4 PF2 a-stretch 755 Ar IR Andrews and Withnall, 1989
e' 5 PH3 a-stretch 2501.7 s T gas IR Seel and Velleman, 1971
Beckers, Breidung, et al., 1990
Beckers, 1993
5 PH3 a-stretch 2480 w b Ar IR Andrews and Withnall, 1989
6 PH3 deform. 965.45 s T gas IR Seel and Velleman, 1971
Beckers, Breidung, et al., 1990
Beckers, 1993
6 PH3 deform. 974 Ar IR Andrews and Withnall, 1989
7 PF2 deform. 341.55 m gas IR Beckers, Burger, et al., 1992
Beckers, 1993

Additional references: Jacox, 1994, page 324; Jacox, 1998, page 315

Notes

wWeak
mMedium
sStrong
vsVery strong
TTentative assignment or approximate value
bBroad

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Seel and Velleman, 1971
Seel, F.; Velleman, K., Die Umsetzung von Diphosphin mit Fluorwasserstoff, Z. Anorg. Allg. Chem., 1971, 385, 1-2, 123, https://doi.org/10.1002/zaac.19713850117 . [all data]

Beckers, Breidung, et al., 1990
Beckers, H.; Breidung, J.; Burger, H.; Kuna, R.; Rahner, A.; Schneider, W.; Thiel, W., High-resolution rotation--vibration spectroscopy of difluorophosphorane: A combined theoretical and experimental study, J. Chem. Phys., 1990, 93, 7, 4603, https://doi.org/10.1063/1.458700 . [all data]

Beckers, 1993
Beckers, H., Eine neue Synthese von H3PF2 durch selektive Fluorierung von H3P. Schwingungsspektren und Normalkoordinatenanalyse der Reihe HnD3?nPF2, Z. Anorg. Allg. Chem., 1993, 619, 11, 1869, https://doi.org/10.1002/zaac.19936191110 . [all data]

Andrews and Withnall, 1989
Andrews, L.; Withnall, R., Cocondensation reaction between phosphine and fluorine: matrix infrared spectra of difluorophosphorane, difluorophosphine and fluorophosphine, Inorg. Chem., 1989, 28, 3, 494, https://doi.org/10.1021/ic00302a023 . [all data]

Beckers, Burger, et al., 1992
Beckers, H.; Burger, H.; Rahner, A., FTIR study of the «nu»7 band of PH3F2 near 340 cm-1, J. Mol. Spectrosc., 1992, 151, 1, 197, https://doi.org/10.1016/0022-2852(92)90015-G . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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