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Zinc Chloride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Reference Comment
32.15760.Bloom and Welch, 1958Based on data from 695. - 826. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.75 ± 0.23EIKiser, Dillard, et al., 1969RDSH
11.802 ± 0.005PEWang, Niu, et al., 1990Vertical value; LL
11.83PEBauschlicher, Rosi, et al., 1990Vertical value; LL
11.85PEBerkowitz, 1974Vertical value; LLK
11.87 ± 0.05PECocksey, Eland, et al., 1973Vertical value; LLK
11.7PEBoggess, Allen, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cl+19.6 ± 0.3?EIKiser, Dillard, et al., 1969RDSH
ZnCl+13.7 ± 0.2ClEIKiser, Dillard, et al., 1969RDSH
Zn+14.6 ± 0.3?EIKiser, Dillard, et al., 1969RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 161241

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bloom and Welch, 1958
Bloom, H.; Welch, B.J., The Vapor Pressure of Cadmium and Zinc Chlorides, J. Phys. Chem., 1958, 62, 12, 1594-1595, https://doi.org/10.1021/j150570a033 . [all data]

Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L., Mass spectrometry of inorganic halides, Advan. Chem. Ser., 1969, 72, 153. [all data]

Wang, Niu, et al., 1990
Wang, L.-S.; Niu, B.; Lee, Y.T.; Shirley, D.A., Electronic structure and chemical bonding of the first row transition metal dichlorides, MnCl2, NiCl2, and ZnCl2: A high resolution photoelectron spectroscopic study, J. Chem. Phys., 1990, 93, 957. [all data]

Bauschlicher, Rosi, et al., 1990
Bauschlicher, C.W., Jr.; Rosi, M.; Langhoff, S.R., The photoelectron spectroscopy of ZnCl2, Chem. Phys., 1990, 146, 237. [all data]

Berkowitz, 1974
Berkowitz, J., PES of high-temperature vapors. VI. 304 A and 584 APES of Zn, Cd, and Hg halides and the electronegativity scale, J. Chem. Phys., 1974, 61, 407. [all data]

Cocksey, Eland, et al., 1973
Cocksey, B.G.; Eland, J.H.D.; Danby, C.J., Photoelectron spectra of the zinc and cadmium halides, J. Chem. Soc. Faraday Trans. 2, 1973, 69, 1558. [all data]

Boggess, Allen, et al., 1973
Boggess, G.W.; Allen, J.D., Jr.; Schweitzer, G.K., The photoelectron spectra of gaseous zinc(II) and cadmium(II) chlorides, bromides, and iodides, J. Electron Spectrosc. Relat. Phenom., 1973, 2, 467. [all data]


Notes

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