Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Naphthalene-D8

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltavap54.7kJ/molCGCZhao, Unhannanant, et al., 2008 

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
70.6 ± 0.5303.GSSonnefeld, Zoller, et al., 1983Based on data from 282. - 323. K.

Gas phase ion energetics data

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.12 ± 0.02TRPIGotkis, Oleinikova, et al., 1993LL
8.12 ± 0.01PIPECORuhl, Price, et al., 1989LL
8.138 ± 0.008SAngus, Christ, et al., 1968RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3D3+19.32(C7D5)PIJochims, Rasekh, et al., 1993LL
C5D3+19.90(C5D5)PIJochims, Rasekh, et al., 1993LL
C6D3+20.5 ± 0.5C4D5PIPECORuhl, Price, et al., 1989LL
C6D4+19.75C4D4PIPECORuhl, Price, et al., 1989LL
C6D5+18.87(C4D3)PIJochims, Rasekh, et al., 1993LL
C6D5+19.5C4D3PIPECORuhl, Price, et al., 1989LL
C6D6+15.83C4D2PIJochims, Rasekh, et al., 1993LL
C6D6+16.1 ± 0.1C4D2PIPECORuhl, Price, et al., 1989LL
C6D7+20.5 ± 0.5C4DPIPECORuhl, Price, et al., 1989LL
C7D3+20.5 ± 0.5C3D5PIPECORuhl, Price, et al., 1989LL
C7D4+20.0 ± 0.1C3D4PIPECORuhl, Price, et al., 1989LL
C7D5+16.60C3D3PIJochims, Rasekh, et al., 1993LL
C7D5+18.0 ± 0.1C3D3PIPECORuhl, Price, et al., 1989LL
C8D5+19.3 ± 0.1C2D3PIPECORuhl, Price, et al., 1989LL
C8D6+15.77C2D2PIJochims, Rasekh, et al., 1993LL
C8D6+12.72C2D2EVALGotkis, Oleinikova, et al., 1993T = 0K; LL
C8D6+14.8 ± 0.1C2D2TRPIGotkis, Oleinikova, et al., 1993LL
C8D6+16.0 ± 0.1C2D2PIPECORuhl, Price, et al., 1989LL
C10D6+<=17.7D2PIPECORuhl, Price, et al., 1989LL
C10D7+15.68DPIJochims, Rasekh, et al., 1993LL
C10D7+12.45DEVALGotkis, Oleinikova, et al., 1993T = 0K; LL
C10D7+15.5 ± 0.1DTRPIGotkis, Oleinikova, et al., 1993LL
C10D7+16.1 ± 0.1DPIPECORuhl, Price, et al., 1989LL

IR Spectrum

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

IR spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 118441

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zhao, Unhannanant, et al., 2008
Zhao, Hui; Unhannanant, Patamaporn; Hanshaw, William; Chickos, James S., Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects, J. Chem. Eng. Data, 2008, 53, 7, 1545-1556, https://doi.org/10.1021/je800091s . [all data]

Sonnefeld, Zoller, et al., 1983
Sonnefeld, W.J.; Zoller, W.H.; May, W.E., Dynamic coupled-column liquid-chromatographic determination of ambient-temperature vapor pressures of polynuclear aromatic hydrocarbons, Anal. Chem., 1983, 55, 2, 275-280, https://doi.org/10.1021/ac00253a022 . [all data]

Gotkis, Oleinikova, et al., 1993
Gotkis, Y.; Oleinikova, M.; Naor, M.; Lifshitz, C., Time-independent mass spectra and breakdown graphs. 17. Naphthalene and phenanthrene, J. Phys. Chem., 1993, 97, 12282. [all data]

Ruhl, Price, et al., 1989
Ruhl, E.; Price, S.D.; Leach, S., Single and double photoionization processes in naphthalene between 8 and 35 eV, J. Phys. Chem., 1989, 93, 6312. [all data]

Angus, Christ, et al., 1968
Angus, J.G.; Christ, B.J.; Morris, G.C., Absorption spectra in the vacuum ultraviolet and the ionization potentials of naphthalene and naphthalene-d, molecules, Australian J. Chem., 1968, 21, 2153. [all data]

Jochims, Rasekh, et al., 1993
Jochims, H.-W.; Rasekh, H.; Ruhl, E.; Baumgartel, H.; Leach, S., Deuterium isotope effects in the photofragmentation of naphthalene monocations, J. Phys. Chem., 1993, 97, 1312. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References