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MgO radical anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.610 ± 0.030N/ACheng, Berkdemir, et al., 2013VDE: 1.61±0.03 eV
1.630 ± 0.025LPESKim, Li, et al., 2001see Vasiliu, Feller, et al., 2010 for support of Operti, Tews, et al., 1989 rather than Gurvich, Veyts, et al. for neutral DfH(MgO)
1.622 ± 0.010LPESGutowski, Skurski, et al., 2000 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cheng, Berkdemir, et al., 2013
Cheng, S.B.; Berkdemir, C.; Melko, J.J.; Castleman, A.W., Probing the Electronic Structures and Relative Stabilities of Monomagnesium Oxide Clusters MgOx- and MgOx (x=1-4): A Combined Photoelectron Imaging and Theoretical Investigation, J. Phys. Chem. A, 2013, 117, 46, 11896-11905, https://doi.org/10.1021/jp403134g . [all data]

Kim, Li, et al., 2001
Kim, J.H.; Li, X.; Wang, L.S.; de Clercq, H.L.; Fancher, C.A.; Thomas, O.C.; Bowen, K.H., Vibrationally resolved photoelectron spectroscopy of MgO- and ZnO- and the low-lying electronic states of MgO, MgO-, and ZnO, J. Phys. Chem. A, 2001, 105, 23, 5709-5718, https://doi.org/10.1021/jp010331d . [all data]

Vasiliu, Feller, et al., 2010
Vasiliu, M.; Feller, D.; Gole, J.L.; Dixon, D.A., Structures and Heats of Formation of Simple Alkaline Earth Metal Compounds: Fluorides, Chlorides, Oxides, and Hydroxides for Be, Mg, and Ca, J. Phys. Chem. A, 2010, 114, 34, 9349-9358, https://doi.org/10.1021/jp1050657 . [all data]

Operti, Tews, et al., 1989
Operti, L.; Tews, E.C.; MacMahon, T.J.; Freiser, B.S., Thermochemical Properties of Gas-Phase MgOH and MgO Determined by Fourier Transform Mass Spectrometry, J. Am. Chem. Soc. (1989), 1989, 111, 26, 9152, https://doi.org/10.1021/ja00208a002 . [all data]

Gurvich, Veyts, et al.
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B., Hemisphere Publishing, NY, 1989, V. 1 2, Thermodynamic Properties of Individual Substances, 4th Ed. [all data]

Gutowski, Skurski, et al., 2000
Gutowski, M.; Skurski, P.; Li, X.; Wang, L.S., (MgO)(n)(-) (n=1-5)clusters: Multipole-bound anions and photodetachment spectroscopy, Phys. Rev. Lett., 2000, 85, 15, 3145-3148, https://doi.org/10.1103/PhysRevLett.85.3145 . [all data]


Notes

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