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Bismuthine, triethyl-

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas216. ± 17.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid170. ± 17.kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Deltacliquid-4961. ± 17.kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
liquid379.0J/mol*KN/ANistratov, Rabinovich, et al., 1989DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
242.2298.15Nistratov, Rabinovich, et al., 1989T = 5 to 330 K. Cp data also given for the glassy state (0-94.8 K) and the supercooled liquid (94.8-145.8 K). T(glass) = 94.8 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple145.8KN/ANistratov, Rabinovich, et al., 1989, 2Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Deltavap46.0 ± 4.2kJ/molCC-SBLautsch, Tröber, et al., 1964MS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
43.9322.Maier, Seyferth, et al., 1957Based on data from 301. - 343. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
8.695145.80Nistratov, Rabinovich, et al., 1989DH
8.7145.8Nistratov, Kabinovich, et al., 1989AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
59.64145.80Nistratov, Rabinovich, et al., 1989DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin ETHYL CORPORATION, FERNDALE, MICHIGAN
NIST MS number 34313

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Nistratov, Rabinovich, et al., 1989
Nistratov, V.P.; Rabinovich, I.B.; Sheiman, M.S.; Smirnova, N.N.; Zelyaev, I.A.; Feshchenko, I.A., Specific heat and thermodyanamic characteristics of triethylbismuth, Zhur. Fiz. Khim., 1989, 63, 1779-1783. [all data]

Nistratov, Rabinovich, et al., 1989, 2
Nistratov, V.P.; Rabinovich, I.B.; Sheiman, M.S.; Smirnova, N.N.; Zelyaev, I.A.; Feshchenko, I.A., Zh. Fiz. Khim., 1989, 1779. [all data]

Lautsch, Tröber, et al., 1964
Lautsch, W.F.; Tröber, A.; Korner, H.; Wagner, K.; Kaden, R.; Blase, S., Z. Chem., 1964, 4, 441. [all data]

Maier, Seyferth, et al., 1957
Maier, Ludwig; Seyferth, Dietmar; Stone, F.G.A.; Rochow, Eugene G., Vinyl Derivatives of the Metals. VI. Preparation, Properties and Some Reactions of Trivinyl Compounds of Group V Elements 1,2, J. Am. Chem. Soc., 1957, 79, 22, 5884-5889, https://doi.org/10.1021/ja01579a012 . [all data]

Nistratov, Kabinovich, et al., 1989
Nistratov, V.P.; Kabinovich, I.B.; Sheiman, M.S.; Smirnova, N.N.; Zelyaev, I.A.; Feshchenko, I.A., Heat capacity and thermodynamic characteristics of triethylbismuth, Zh. Fiz. Khim., 1989, 63, 7, 1779. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References