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Cubane-1,4-dicarboylic acid dimethyl ester

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus437.8KN/AKirklin, Churney, et al., 1989Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap21.2 ± 0.53kcal/molCGCRoux, Dávalos, et al., 2005AC
Quantity Value Units Method Reference Comment
Deltasub28.01 ± 0.93kcal/molVap+FusRoux, Dávalos, et al., 2005AC
Deltasub28.42 ± 0.91kcal/molEKirklin, Churney, et al., 1989, 2ALS

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Method Reference Comment
9.7992437.8N/AKirklin, Churney, et al., 1989, 2DH
9.11438.2DSCRoux, Dávalos, et al., 2005AC
9.80437.8N/ADomalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
22.4437.8Kirklin, Churney, et al., 1989, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kirklin, Churney, et al., 1989
Kirklin, D.R.; Churney, K.L.; Domalski, E.S., Enthalpy of combustion of 1,4-dimethylcubane dicarboxylate, J. Chem. Thermodyn., 1989, 21, 1105. [all data]

Roux, Dávalos, et al., 2005
Roux, Maria Victoria; Dávalos, Juan Z.; Jiménez, Pilar; Notario, Rafael; Castaño, Obis; Chickos, James S.; Hanshaw, William; Zhao, Hui; Rath, Nigam; Liebman, Joel F.; Farivar, Behzad S.; Bashir-Hashemi, A., Cubane, Cuneane, and Their Carboxylates: A Calorimetric, Crystallographic, Calculational, and Conceptual Coinvestigation, J. Org. Chem., 2005, 70, 14, 5461-5470, https://doi.org/10.1021/jo050471+ . [all data]

Kirklin, Churney, et al., 1989, 2
Kirklin, D.R.; Churney, K.L.; Domalski, E.S., Enthalpy of combustion of 1,4-dimethylcubane dicarboxylate, J. Chem. Thermodyn., 1989, 21, 1105-1113. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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