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HypoFluorous acid

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
IE (evaluated)12.71 ± 0.01eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
12.69 ± 0.03PEBerkowitz, Dehmer, et al., 1973LLK
12.71 ± 0.01PIBerkowitz, Appelman, et al., 1973LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
HO+15.07FPIBerkowitz, Appelman, et al., 1973LLK
O+14.34HFPIBerkowitz, Appelman, et al., 1973LLK

De-protonation reactions

FO- + Hydrogen cation = HypoFluorous acid

By formula: FO- + H+ = HFO

Quantity Value Units Method Reference Comment
Deltar1517. ± 14.kJ/molAcidGilles, Polak, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar1490. ± 15.kJ/molH-TSGilles, Polak, et al., 1992gas phase; B

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Dehmer, et al., 1973
Berkowitz, J.; Dehmer, J.L.; Appelman, E.H., Photoelectron spectrum of hypofluorous acid, HOF, Chem. Phys. Lett., 1973, 19, 334. [all data]

Berkowitz, Appelman, et al., 1973
Berkowitz, J.; Appelman, E.H.; Chupka, W.A., Photoionization of HOF with mass analysis, J. Chem. Phys., 1973, 58, 1950. [all data]

Gilles, Polak, et al., 1992
Gilles, M.K.; Polak, M.L.; Lineberger, W.C., Photoelectron Spectroscopy of the Halogen Oxide Anions FO-, ClO-, BrO-, IO-, OClO-, and OIO-, J. Chem. Phys., 1992, 96, 11, 8012, https://doi.org/10.1063/1.462352 . [all data]


Notes

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