PH2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   a
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 5650 gas Berkowitz, Curtiss, et al., 1986
Berkowitz and Cho, 1989
Chau, Dyke, et al., 1997

State:   A

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 Bend 888 ± 80 gas PE Chau, Dyke, et al., 1997

Additional references: Jacox, 1994, page 21; Jacox, 2003, page 18

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Curtiss, et al., 1986
Berkowitz, J.; Curtiss, L.; Gibson, S.; Greene, J.; Hillhouse, G.; Pople, J., Photoionization mass spectrometric study and Ab initio calculation of ionization and bonding in P-H compounds. Heats of formation, bond energies, and the 3B1-1A1 separation in PH2+, J. Chem. Phys., 1986, 84, 375. [all data]

Berkowitz and Cho, 1989
Berkowitz, J.; Cho, H., A photoionization study of PH: PH2 revisited, J. Chem. Phys., 1989, 90, 1, 1, https://doi.org/10.1063/1.456522 . [all data]

Chau, Dyke, et al., 1997
Chau, F.-T.; Dyke, J.M.; Lee, E.P.F.; Ridha, A.; Wang, D.-C., HeI photoelectron spectra of PH2 and PF2: comparison between simulation and experiment, Chem. Phys., 1997, 224, 2-3, 157, https://doi.org/10.1016/S0301-0104(97)00253-X . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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