Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Phenylthio radical


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 32260 T gas Porter and Wright, 1955

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 19328 ± 4 gas B-X 490 600 Shibuya, Nemoto, et al., 1988


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Ring deform. 483 ± 5 gas LF Shibuya, Nemoto, et al., 1988
CS stretch 410 ± 5 gas LF Shibuya, Nemoto, et al., 1988
CH deform. 275 ± 5 gas LF Shibuya, Nemoto, et al., 1988

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

CH deform. 1165 ± 20 gas LF Shibuya, Nemoto, et al., 1988
Ring deform. 610 ± 20 gas LF Shibuya, Nemoto, et al., 1988
CS stretch 430 ± 20 gas LF Shibuya, Nemoto, et al., 1988

Additional references: Jacox, 1994, page 443

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Porter and Wright, 1955
Porter, G.; Wright, F.J., Primary photochemical processes in aromatic molecules. Part 3. Absorption spectra of benzyl, anilino, phenoxy and related free radicals, Trans. Faraday Soc., 1955, 51, 1469, https://doi.org/10.1039/tf9555101469 . [all data]

Shibuya, Nemoto, et al., 1988
Shibuya, K.; Nemoto, M.; Yanagibori, A.; Fukushima, M.; Obi, K., Spectroscopy and kinetics of thiophenoxy radicals in the gas phase, Chem. Phys., 1988, 121, 2, 237, https://doi.org/10.1016/0301-0104(88)90030-4 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References