Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

HOSO2


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

OH stretch 3539.8 m Ar IR Hashimoto, Inoue, et al., 1984
Nagase, Hashimoto, et al., 1988
Kuo, Cheng, et al., 1991
OH stretch 3475.5 N2 IR Wierzejewska and Olbert-Majkut, 2003
SO2 a-stretch 1309.2 s Ar IR Hashimoto, Inoue, et al., 1984
Nagase, Hashimoto, et al., 1988
Kuo, Cheng, et al., 1991
SO2 a-stretch 1311.7 s N2 IR Wierzejewska and Olbert-Majkut, 2003
HOS bend 1296.2 w m Ar IR Kuo, Cheng, et al., 1991
SO2 s-stretch 1097.2 s Ar IR Hashimoto, Inoue, et al., 1984
Nagase, Hashimoto, et al., 1988
Kuo, Cheng, et al., 1991
SO2 s-stretch 1102.6 N2 IR Wierzejewska and Olbert-Majkut, 2003
S-OH stretch 759.3 s Ar IR Hashimoto, Inoue, et al., 1984
Nagase, Hashimoto, et al., 1988
Kuo, Cheng, et al., 1991
S-OH stretch 786.8 N2 IR Wierzejewska and Olbert-Majkut, 2003
OPLA 538.4 w m N2 IR Wierzejewska and Olbert-Majkut, 2003

Additional references: Jacox, 1994, page 277

Notes

wWeak
mMedium
sStrong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hashimoto, Inoue, et al., 1984
Hashimoto, S.; Inoue, G.; Akimoto, H., Infrared spectroscopic detection of the HOSO2 radical in argon matrix at 11 k, Chem. Phys. Lett., 1984, 107, 2, 198, https://doi.org/10.1016/0009-2614(84)85699-7 . [all data]

Nagase, Hashimoto, et al., 1988
Nagase, S.; Hashimoto, S.; Akimoto, H., Bisulfite and peroxybisulfate radicals studied by ab initio calculation and matrix isolation technique, J. Phys. Chem., 1988, 92, 3, 641, https://doi.org/10.1021/j100314a015 . [all data]

Kuo, Cheng, et al., 1991
Kuo, Y.-P.; Cheng, B.-M.; Lee, Y.-P., Production and trapping of HOSO2 from the gaseous reaction OH+SO2: the infrared absorption of HOSO2 in solid argon, Chem. Phys. Lett., 1991, 177, 2, 195, https://doi.org/10.1016/0009-2614(91)90067-J . [all data]

Wierzejewska and Olbert-Majkut, 2003
Wierzejewska, M.; Olbert-Majkut, A., Photolysis of Matrix Isolated HONO/SO, J. Phys. Chem. A, 2003, 107, 50, 10944, https://doi.org/10.1021/jp036073x . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References