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ClOClO3


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 42740 gas Lopez and Sicre, 1988

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 ClO2 s-stretch 1283 vs gas IR Schack and Pilipovich, 1970
Christe, Schack, et al., 1971
Schell-Sorokin, Bethune, et al., 1982
Burkholder, Orlando, et al., 1990
1 ClO2 s-stretch 1293.2 Ne IR Muller and Willner, 1993
1 ClO2 s-stretch 1287 vs Ar IR Christe, Schack, et al., 1971
2 Cl=O stretch 1040 s gas IR Schack and Pilipovich, 1970
Christe, Schack, et al., 1971
2 Cl=O stretch 1040.2 Ne IR Muller and Willner, 1993
2 Cl=O stretch 1039 s Ar IR Christe, Schack, et al., 1971
3 O-Cl stretch 749 w m gas IR Schack and Pilipovich, 1970
Christe, Schack, et al., 1971
3 O-Cl stretch 747.5 Ne IR Muller and Willner, 1993
3 O-Cl stretch 746 m Ar IR Christe, Schack, et al., 1971
4 Cl-O stretch 646 vs gas IR Schack and Pilipovich, 1970
Christe, Schack, et al., 1971
4 Cl-O stretch 652.1 Ne IR Muller and Willner, 1993
4 Cl-O stretch 647 vs Ar IR Christe, Schack, et al., 1971
5 O=Cl=O bend 580 s gas IR Christe, Schack, et al., 1971
5 O=Cl=O bend 586.9 Ne IR Muller and Willner, 1993
5 O=Cl=O bend 582 m Ar IR Christe, Schack, et al., 1971
6 ClO3 deform. 511 w m gas IR Christe, Schack, et al., 1971
6 ClO3 deform. 514.6 Ne IR Muller and Willner, 1993
6 ClO3 deform. 513 m Ar IR Christe, Schack, et al., 1971
7 O=Cl-O bend 355 w Ar IR Christe, Schack, et al., 1971
a 9 ClO2 a-stretch 1283 vs gas IR Schack and Pilipovich, 1970
Christe, Schack, et al., 1971
Schell-Sorokin, Bethune, et al., 1982
Burkholder, Orlando, et al., 1990
9 ClO2 a-stretch 1277.6 Ne IR Muller and Willner, 1993
9 ClO2 a-stretch 1271 vs Ar IR Christe, Schack, et al., 1971
10 O=Cl=O bend 561 m gas IR Christe, Schack, et al., 1971
10 O=Cl=O bend 565.3 Ne IR Muller and Willner, 1993
10 O=Cl=O bend 561 m s Ar IR Christe, Schack, et al., 1971
11 O=Cl-O bend 382 w Ar IR Christe, Schack, et al., 1971

Additional references: Jacox, 1994, page 355; Jacox, 1998, page 322

Notes

wWeak
mMedium
sStrong
vsVery strong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lopez and Sicre, 1988
Lopez, M.I.; Sicre, J.E., Ultraviolet spectrum of chlorine perchlorate, J. Phys. Chem., 1988, 92, 2, 563, https://doi.org/10.1021/j100313a062 . [all data]

Schack and Pilipovich, 1970
Schack, C.J.; Pilipovich, D., Chlorine perchlorate, Inorg. Chem., 1970, 9, 6, 1387, https://doi.org/10.1021/ic50088a019 . [all data]

Christe, Schack, et al., 1971
Christe, K.O.; Schack, C.J.; Curtis, E.C., Halogen perchlorates. Vibrational spectra, Inorg. Chem., 1971, 10, 8, 1589, https://doi.org/10.1021/ic50102a009 . [all data]

Schell-Sorokin, Bethune, et al., 1982
Schell-Sorokin, A.J.; Bethune, D.S.; Lankard, J.R.; Loy, M.M.T.; Sorokin, P.P., Chlorine perchlorate a major photolysis product of chlorine dioxide, J. Phys. Chem., 1982, 86, 24, 4653, https://doi.org/10.1021/j100221a001 . [all data]

Burkholder, Orlando, et al., 1990
Burkholder, J.B.; Orlando, J.J.; Howard, C.J., Ultraviolet absorption cross sections of chlorine oxide (Cl2O2) between 210 and 410 nm, J. Phys. Chem., 1990, 94, 2, 687, https://doi.org/10.1021/j100365a033 . [all data]

Muller and Willner, 1993
Muller, H.S.P.; Willner, H., Vibrational and electronic spectra of chlorine dioxide, OClO, and chlorine superoxide ClOO, isolated in cryogenic matrixes, J. Phys. Chem., 1993, 97, 41, 10589, https://doi.org/10.1021/j100143a013 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References