1,2,3-Trioxolane


Gas phase thermochemistry data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Glushko Thermocenter, Russian Academy of Sciences, Moscow

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
9.38350.Dorofeeva O.V., 1992p=1 bar.
11.01100.
12.31150.
14.07200.
17.39273.15
18.6 ± 1.1298.15
18.72300.
23.54400.
27.620500.
30.887600.
33.511700.
35.655800.
37.433900.
38.9241000.
40.1841100.
41.2571200.
42.1751300.
42.9611400.
43.6401500.

Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

CH2 deform. 1214 m Xe IR Kohlmiller and Andrews, 1981
CO st., CH2def. 983 s Xe IR Kohlmiller and Andrews, 1981
CO st., CH2def. 982 CO2 IR Nelander and Nord, 1977
Kohlmiller and Andrews, 1981
CO stretch 927 s Xe IR Kohlmiller and Andrews, 1981
CO stretch 926 CO2 IR Nelander and Nord, 1977
Kohlmiller and Andrews, 1981
O3 s-stretch 846 w m Xe IR Kohlmiller and Andrews, 1981
COO def.,CO st. 727 vs Xe IR Kohlmiller and Andrews, 1981
COO def.,CO st. 726 CO2 IR Nelander and Nord, 1977
Kohlmiller and Andrews, 1981
O3 a-stretch 647 vs Xe IR Kohlmiller and Andrews, 1981
O3 a-stretch 648 CO2 IR Nelander and Nord, 1977
Kohlmiller and Andrews, 1981
O3 bend 409 m Xe IR Kohlmiller and Andrews, 1981
O3 bend 406 CO2 IR Nelander and Nord, 1977
Kohlmiller and Andrews, 1981

Additional references: Jacox, 1994, page 422; Jacox, 1998, page 366; Zozom, Gillies, et al., 1987; Gillies, Gillies, et al., 1988

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dorofeeva O.V., 1992
Dorofeeva O.V., Ideal gas thermodynamic properties of oxygen heterocyclic compounds. Part 1. Three-membered, four-membered and five-membered rings, Thermochim. Acta, 1992, 194, 9-46. [all data]

Kohlmiller and Andrews, 1981
Kohlmiller, C.K.; Andrews, L., Infrared spectrum of the primary ozonide of ethylene in solid xenon, J. Am. Chem. Soc., 1981, 103, 10, 2578, https://doi.org/10.1021/ja00400a016 . [all data]

Nelander and Nord, 1977
Nelander, B.; Nord, L., Tetrahedron Lett., 1977, 2821. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Zozom, Gillies, et al., 1987
Zozom, J.; Gillies, C.W.; Suenram, R.D.; Lovas, F.J., Microwave detection of the primary ozonide of ethylene in the gas phase, Chem. Phys. Lett., 1987, 140, 1, 64, https://doi.org/10.1016/0009-2614(87)80418-9 . [all data]

Gillies, Gillies, et al., 1988
Gillies, J.Z.; Gillies, C.W.; Suenram, R.D.; Lovas, F.J., The ozonolysis of ethylene. Microwave spectrum, molecular structure, and dipole moment of ethylene primary ozonide (1,2,3-trioxolane), J. Am. Chem. Soc., 1988, 110, 24, 7991, https://doi.org/10.1021/ja00232a007 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References