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Silver trimer


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 31150 Ar Fedrigo, Harbich, et al., 1993
Rabin, Schulze, et al., 2000

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 28570 Ar Rabin, Schulze, et al., 2000

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 27550 Ar Rabin, Schulze, et al., 2000

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 26700 Ar Fedrigo, Harbich, et al., 1993
Rabin, Schulze, et al., 2000

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 30200 Kr Harbich, Fedrigo, et al., 1990

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 26200 Kr Harbich, Fedrigo, et al., 1990

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 27500 Kr Harbich, Fedrigo, et al., 1990

State:   2E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 26969.0 gas 2E''-X 365 385 Cheng and Duncan, 1988
LaiHing, Cheng, et al., 1989
Ellis, Robles, et al., 1993
Wedum, Grant, et al., 1994
Sioutis, Stakhursky, et al., 2007
Tx = 25900 Ar 2E''-X Fedrigo, Harbich, et al., 1993
Tx = 26200 Kr 2E''-X Harbich, Fedrigo, et al., 1990


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 Sym. stretch 158.2 gas MPI LF Cheng and Duncan, 1988
LaiHing, Cheng, et al., 1989
Ellis, Robles, et al., 1993
Wedum, Grant, et al., 1994
Sioutis, Stakhursky, et al., 2007
e' 2 Deformation 100.5 gas MPI LF Cheng and Duncan, 1988
LaiHing, Cheng, et al., 1989
Ellis, Robles, et al., 1993
Wedum, Grant, et al., 1994

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 24900 Kr Harbich, Fedrigo, et al., 1990

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 23870 Ar Schulze, Becker, et al., 1978
Ozin, Huber, et al., 1979
Harbich, Fedrigo, et al., 1990
Rabin, Schulze, et al., 2000

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 23470 Ar Rabin, Schulze, et al., 2000

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 23700 Kr Schulze, Becker, et al., 1978
Ozin, Huber, et al., 1979
Harbich, Fedrigo, et al., 1990

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 23700 Xe Schulze, Becker, et al., 1978
Ozin, Huber, et al., 1979
Harbich, Fedrigo, et al., 1990

State:   2A1' ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 19809 ± 2 gas 495 505 Okazaki, Saito, et al., 1996
Tx = 20490 Ar Rabin, Schulze, et al., 2000
Tx = 20300 Ar Fedrigo, Harbich, et al., 1993
Rabin, Schulze, et al., 2000
Tx = 19880 Ar Rabin, Schulze, et al., 2000
Tx = 16450 Ar Rabin, Schulze, et al., 2000
Tx = 16180 Ar Rabin, Schulze, et al., 2000
Tx = 16100 Ar Fedrigo, Harbich, et al., 1993
Rabin, Schulze, et al., 2000
Tx = 21830 Kr Harbich, Fedrigo, et al., 1990
Tx = 19500 Kr Harbich, Fedrigo, et al., 1990
Tx = 17900 Kr Harbich, Fedrigo, et al., 1990
Tx = 16000 Kr Harbich, Fedrigo, et al., 1990


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 Sym. stretch 107 gas EM Okazaki, Saito, et al., 1996
e' 2 Deformation 94 gas EM Okazaki, Saito, et al., 1996

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 Sym. stretch 121 gas LF Ellis, Robles, et al., 1993
Wedum, Grant, et al., 1994
Sioutis, Stakhursky, et al., 2007
1 Sym. stretch 119 Ar Ra Haslett, Bosnick, et al., 1999
1 Sym. stretch 120 T Kr Ra Schulze, Becker, et al., 1978, 2
e' 2 Deformation 67 gas LF Sioutis, Stakhursky, et al., 2007

Additional references: Jacox, 1994, page 60; Jacox, 1998, page 161; Jacox, 2003, page 52

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fedrigo, Harbich, et al., 1993
Fedrigo, S.; Harbich, W.; Buttet, J., Optical response of Ag2, Ag3, Au2, and Au3 in argon matrices, J. Chem. Phys., 1993, 99, 8, 5712, https://doi.org/10.1063/1.465920 . [all data]

Rabin, Schulze, et al., 2000
Rabin, I.; Schulze, W.; Ertl, G.; Felix, C.; Sieber, C.; Harbich, W.; Buttet, J., Absorption and fluorescence spectra of Ar-matrix-isolated Ag3 clusters, Chem. Phys. Lett., 2000, 320, 1-2, 59, https://doi.org/10.1016/S0009-2614(00)00211-6 . [all data]

Harbich, Fedrigo, et al., 1990
Harbich, W.; Fedrigo, S.; Meyer, F.; Lindsay, D.M.; Lignieres, J.; Rivoal, J.C.; Kreisle, D., Deposition of mass selected silver clusters in rare gas matrices, J. Chem. Phys., 1990, 93, 12, 8535, https://doi.org/10.1063/1.459291 . [all data]

Cheng and Duncan, 1988
Cheng, P.Y.; Duncan, M.A., Vibronic spectroscopy and dynamics in the jet-cooled silver trimer, Chem. Phys. Lett., 1988, 152, 4-5, 341, https://doi.org/10.1016/0009-2614(88)80103-9 . [all data]

LaiHing, Cheng, et al., 1989
LaiHing, K.; Cheng, P.Y.; Duncan, M.A., Laser photoionization and spectroscopy of gas phase silver clusters, Z. Phys. D, 1989, 13, 2, 161, https://doi.org/10.1007/BF01398586 . [all data]

Ellis, Robles, et al., 1993
Ellis, A.M.; Robles, E.S.J.; Miller, T.A., Dispersed fluorescence spectroscopic study of the ground electronic state of silver trimer, Chem. Phys. Lett., 1993, 201, 1-4, 132, https://doi.org/10.1016/0009-2614(93)85046-Q . [all data]

Wedum, Grant, et al., 1994
Wedum, E.E.; Grant, E.R.; Cheng, P.Y.; Willey, K.F.; Duncan, M.A., On the assignment of Jahn--Teller effects in the ultraviolet absorption spectrum of Ag3, J. Chem. Phys., 1994, 100, 9, 6312, https://doi.org/10.1063/1.467093 . [all data]

Sioutis, Stakhursky, et al., 2007
Sioutis, I.; Stakhursky, V.L.; Pitzer, R.M.; Miller, T.A., Jahn-Teller and related effects in the silver trimer. II: Vibrational analysis of the A [sup 2]E[sup ´´]-X [sup 2]E[sup ´] electronic transition, J. Chem. Phys., 2007, 126, 12, 124309, https://doi.org/10.1063/1.2430704 . [all data]

Schulze, Becker, et al., 1978
Schulze, W.; Becker, H.U.; Abe, H., The preparation of silver molecules Agn (n < 10) in Kr matrices and their ultraviolet-visible absorption spectra, Chem. Phys., 1978, 35, 1-2, 177, https://doi.org/10.1016/0301-0104(78)85203-3 . [all data]

Ozin, Huber, et al., 1979
Ozin, G.A.; Huber, H.; Mitchell, S.A., Selective, naked cluster cryophotochemistry: trisilver, Ag3, Inorg. Chem., 1979, 18, 10, 2932, https://doi.org/10.1021/ic50200a065 . [all data]

Okazaki, Saito, et al., 1996
Okazaki, T.; Saito, Y.; Kasuya, A.; Nishina, Y., Optical emission spectra of Ag3 molecules in the gas evaporation technique, J. Chem. Phys., 1996, 104, 3, 812, https://doi.org/10.1063/1.470806 . [all data]

Haslett, Bosnick, et al., 1999
Haslett, T.L.; Bosnick, K.A.; Fedrigo, S.; Moskovits, M., Resonance Raman spectroscopy of matrix-isolated mass-selected Fe[sub 3] and Ag[sub 3], J. Chem. Phys., 1999, 111, 14, 6456, https://doi.org/10.1063/1.480014 . [all data]

Schulze, Becker, et al., 1978, 2
Schulze, W.; Becker, H.U.; Minkwitz, R.; Manzel, K., Matrix Raman spectra of Ag2 and Ag3, Chem. Phys. Lett., 1978, 55, 1, 59, https://doi.org/10.1016/0009-2614(78)85132-X . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References