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Ferric tris(acetylacetonate)

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus461.KN/AMurray and Hill, 1984Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Deltasub128.6 ± 0.9kJ/molN/ARibeiro da Silva, Monte, et al., 1996AC
Deltasub126.4 ± 3.1kJ/molMEMalkerova, Alikhanyan, et al., 1990Based on data from 309. - 360. K.; AC
Deltasub138.4 ± 5.2kJ/molCMurata, Sakiyama, et al., 1985AC
Deltasub65.3 ± 3.3kJ/molN/APilcher and Skinner, 1983See also Hill and Irving, 1968.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
112.413. - 443.TGAFahlman and Barron, 2000AC
124.6 ± 0.9378.TE,MERibeiro da Silva, Monte, et al., 1996Based on data from 369. - 388. K.; AC
114.2 ± 1.5338. - 355.N/AGerasimova, Gerasimova, et al., 1992AC
100.395.TMaslowska and Baranowski, 1981AC
114.2385.N/AGötze, Bloss, et al., 1970AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
30.1459.DSCSabolovic, Mrak, et al., 2004AC
25.3460.DSCSabolovic, Mrak, et al., 2004AC
22.6462.N/AMurray and Hill, 1984, 2AC
25.9454.N/AMelia and Merrifield, 1970AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murray and Hill, 1984
Murray, J.P.; Hill, J.O., DSC determination of the fusion and sublimation enthalpy of tris(2,4-pentanedionato)chromium(III) and iron(III), Thermochim. Acta, 1984, 72, 341. [all data]

Ribeiro da Silva, Monte, et al., 1996
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Huinink, Jan, Vapour pressures and standard molar enthalpies of sublimation of two crystalline iron(III) «beta»-diketonates. The mean molar (Fe-O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1996, 28, 4, 413-419, https://doi.org/10.1006/jcht.1996.0041 . [all data]

Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I., Thermal behavior of 3d transition metal acetylacetonates, Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]

Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S., Sublimation calorimetric studies using a calvet microcalorimeter, Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Hill and Irving, 1968
Hill, J.O.; Irving, R.J., The heat of formation of tris(acetylacetonato)iron(III) and the metal?oxygen bond energy, J. Chem. Soc., A, 1968, 1052, https://doi.org/10.1039/j19680001052 . [all data]

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

Gerasimova, Gerasimova, et al., 1992
Gerasimova, P.A.; Gerasimova, A.I.; Fedotova, N.E.; Morozova, N.B.; Igumenov, I.K., Thermochemical study of iron(III) tris(«beta»-diketonates), Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1992, 35, 9, 38. [all data]

Maslowska and Baranowski, 1981
Maslowska, J.; Baranowski, J.B., Chemia Analityczna, 1981, 26, 1017. [all data]

Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H., Dampfdruckbestimmung von Acetylacetonaten, Zeitschrift für Physikalische Chemie, 1970, 73, 46, 314-320, https://doi.org/10.1524/zpch.1970.73.46.314 . [all data]

Sabolovic, Mrak, et al., 2004
Sabolovic, Jasmina; Mrak, Zeljko; Kostrun, Sanja; Janekovic, August, Is the Enthalpy of Fusion of Tris(acetylacetonato)metal(III) Complexes Affected by Their Potential Energy in the Crystal State?, Inorg. Chem., 2004, 43, 26, 8479-8489, https://doi.org/10.1021/ic048900u . [all data]

Murray and Hill, 1984, 2
Murray, J.P.; Hill, J.O., DSC determination of the fusion and sublimation enthalpy of tris(2,4-pentanedionato)chromium(III) and iron(III), Thermochimica Acta, 1984, 72, 3, 341-347, https://doi.org/10.1016/0040-6031(84)85092-3 . [all data]

Melia and Merrifield, 1970
Melia, T.P.; Merrifield, R., Thermal properties of transition metal compounds, Journal of Inorganic and Nuclear Chemistry, 1970, 32, 8, 2573-2579, https://doi.org/10.1016/0022-1902(70)80304-9 . [all data]


Notes

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